不同溶剂中热解制备pd基三元金属催化剂及其对乙醇的电催化性能的研究物理化学专业论文.docxVIP

活性。3、将不同方法处理过的石墨烯(水热法处理的石墨烯记作石墨烯a，0．5M 活性。 3、将不同方法处理过的石墨烯(水热法处理的石墨烯记作石墨烯a，0．5M NaOH处理的石墨烯记作石墨烯b、1．5M NaOH处理的石墨烯记作石墨烯c)分 别与相同量的PdO混合后，通过研磨的方法制备成催化剂后，对乙醇进行一系 列的电化学催化氧化测试，通过x射线衍射()(】m)、扫描电子显微镜(SEM) 和透射电子显微镜(TEM)主要看到样品的晶型和形貌，主要采用循环伏安法 (CV)和计时电流法(CA)对直接乙醇燃料电池(DEFCs)的重要阳极反应中 乙醇氧化反应(EOR)进行关于所制备的催化剂的检测，研究发现，石墨烯b+PdO 对乙醇的电催化活性最好。 4、以离子液体1．丁基．3．甲基咪唑三氟乙酸盐为溶剂，用PdO分别和石墨烯， 乙炔黑，多壁碳纳米管(MwCNTs)制备催化剂对乙醇进行电催化行为的研究。 通过X射线衍射()(1m)、扫描电子显微镜(SEM)和透射电子显微镜(TEM) 主要看到样品的晶型和形貌，主要采用循环伏安法(CV)和计时电流法(cA) 对直接乙醇燃料电池(DEFCs)的重要阳极反应中乙醇氧化反应(EOR)进行关 于所制备的催化剂的检测，研究发现，PdO+石墨烯对乙醇的电催化活性最好。 关键词：三元合金催化剂EOR热解离子液体石墨烯 万方数据 Abs仃actCompared Abs仃act Compared with methanol，ethanol possessed many superior properties such as high energy density and lower toxicity．Most importantly,ethanol could be produced massively from agricultural products by fermentation．Therefore，ethanol oxidation reaction(EOR)has become into a hot topic in the research field of electrochemistry． Of late，it was demonstrated that palladium(Pd)is a good electro-catalyst for ethanol oxidation especially in alkaline media．Therefore，Pd and Pd-based electrocatalysts are extensively studied mainly owing to its similar electronic structure，lower cost and more abundance on the earth when compared with Pt．In this thesis，The crystalline phases and morphologies of the samples were mainly featured using X-ray diffraction (XRD)，scanning electron microscope(SEM)and transmission electron microscopy (TEM)．Explore catalyst prepared electrocatalytic activity of ethanol through a series of electrochemical test methods． The main experiment as follows： 1、A series of trimetallic PdlNiyAl0．5 composite nanoparficles(the nominal atomic ratios of Pd：Ni：A1 were 1：2：O．5，1：4：0．5 and 1：6：O．5，respectively)were produced onto multi—walled carbon nanotubes(MWCNTs)(denoted as Pd INiyAlo．5／MWCNTs)using a hydrothermal process．The crystalline phasesand morphologies of the samples were mainly featured using X-ray diffraction(XRD)， scanning electron microscope(SEM)and transmis