电感耦合等离子体原子发射光谱法测定石油化工废催化剂中铂的含量.PDFVIP

PerkinElmer80 周年用户论文集 电感耦合等离子体原子发射光谱法测定石油化工废催化剂中铂 的含量 郁丰善 （江西省汉氏贵金属有限公司，江西省万年县335500 ） 摘要：本文研究了石油化工铝硅载体废催化剂中铂含量的电感耦合等离子体原子发射光谱测定方法。样品 以硫酸溶解石油化工铝硅载体废催化剂，用氯气氧化络合铂进入溶液，在2%(v/v)硫酸条件下，用标准曲 线法对废催化剂中的Pt 进行测定，可精确测定0.100～0.800%含量的铂，常见的杂质元素不干扰测定。结 果表明：以低浓度硫酸为介质，用标准曲线法进行样品分析，方法的检出限为0.010µg/mL，样品的加标 回收率为97.2— 101.8%。通过试验结果可知该方法准确性好、精密度高，方法准确快速，操作简单。 关键词：石油化工铝硅载体废催化剂；铂；ICP-AES ；标准曲线法。 Determination of platinum in waste catalyst of petrochemical industry by inductively coupled plasma atomic emission spectrometry (Yu Fengshan) (Jiangxi Province Hans Precious Metals Co.,Ltd. Jiangxi Province 335500) Abstract: The method od inductively coupled plasma atomic emission spectrometry for the determination of platinum content in waste catalyst of aluminium silicon supports in petrochemical industry was studied. Samples with sulfuric acid dissolved petroleum chemical waste aluminum silicon carrier catalyst into the solution by under the conditions of sulfuric acid,waste catalyst chlorine oxidation and complexation of platinum,in 2% (v/v ） in Pt was determined by standard curve method, accurate determination of 0.100~0.800% content of platinum, 178 PerkinElmer80 周年用户论文集 common impurity elements do not interfere with the determination. The results showed that the low concentration of sulfuric acid as meduim, method of sample analysisi using standard curve method, the detection limit was 0.01g/mL, the recoveries ranged from 97.2% to 101.8%. The test result shows that this method has the advantages of high accuracy, high precision, accuracy, speed and simple operation. Keywords: Petrochemical alu