具有异氰尿酸骨架结构的多元羧酸配体构筑的金属有机配位聚合物的合成结构与性能研究化学工程与技术专业论文.docxVIP

物lO中，配体采取V型构造，形成一维的MONT，这些一维的MONT通 物lO中，配体采取V型构造，形成一维的MONT，这些一维的MONT通 过Pb．O键连接成二维面状结构，其与游离水在氢键作用下形成三维超分子 网络。同时配位聚合物9和10具有很好的荧光性能。 (3)选取金属Ag(I)离子分别与H3tci和H2bci配体配位得到配位聚合物 11和12：{[A93(tci)。n20]}n(11)、{[Ag(bci)0．5】·0．5H20}。02)。配位聚合物1l 晶胞中存在着三种晶体学独立的金属，形成{A92}2+二聚体结构，此结构连 接羧基氧形成{A9202)次级结构单元，与配体连接成独立的Ag．Ag链，相邻 Ag．Ag链通过配体的柔性丙酸基相互交接成三维网络结构，拓扑简化得4 节点(4，5，5，6)．连接的三维模型。其中，配位聚合物12与10为同种实验条 件下用不同金属合成的异质同晶结构；结构同配位聚合物10，12也展示出 包含一维MONT的三维超分子网络。同时，配位聚合物11和12具有很好 的荧光性。 关键词：配位聚合物，异氰尿酸---(2-羧乙基)酯，异氰尿酸双(2．羧乙基)酯， 荧光，拓扑结构 万方数据 Construction，Structures Construction，Structures and Characterizations of Metal-Organic Coordination Polymers with Multicarboxylate Ligand containing Isocyanuric Framework ABSTRACT Witll the development of coordination chemistry, metal—organic coordination polymers，as potential multifunctional material，which have attracted great research interest from domestic and overseas．Design and synthesis of multifunctional materials have become the hot spot to researchers． Metal·organic coordination polymers gathered together with the properties of organic chemistry and inorganic chemistry,which not only have intriguing variety of architectures and topologies，but also have fascinating potential applications in optics，magnetism，electricity,energy storage，environmental protection and pharmaceuticals． In this dissertation，we focus on two kinds of multicarboxylate ligands containing isocyanuric framework：tris(2-carboxyethyl)isocyanurate(H3tci)and bis(2一carboxyethyl)isocyanurate(H2bci)，under the intervention of various lanthanide，main group and transition metal ions．Twelve special construction coordination polymers have been synthesized under hydrothermal conditions． Furthermore，the influence factors on the structures of coordination polymers are also discussed．All crystalline polymers have been characterized by single—crystal， IR，element analysis，XRD，TGA and fluorescence．The major contents of this dissertation are listed as follows： 1．Eight coordination polymers have be