超声fenton联合降解印染污泥中多环芳烃的研究环境科学与工程专业论文.docxVIP

广东工业大学硕士学位论文PAHs的降解效果。然而，在较少·OH自由基的存在下，高声能密度产生的 广东工业大学硕士学位论文 PAHs的降解效果。然而，在较少·OH自由基的存在下，高声能密度产生的 高能量有利于高环PAHs的降解并进一步分解为低环PAHs，使得高环PAHs 的去除率高于低环PAHs。经CCD响应曲面法优化后的降解条件为：H202 投加量为1 52 mmol／L，声能密度为408 W／L，初始pH值3．7，H202：Fe2十 的摩尔比为1．3：1，反应时间为43 min。通过实验可得优化后Y．PAHs的去 除率为83．9％，实验值与预测值(85．O％)接近。 关键词：多环芳烃；印染污泥；超声；Fenton；持久性有机污染物 万方数据 ABSTRACTABSTRACT ABSTRACT ABSTRACT Textile dyeing sludge is the primary solid waste created during textile dyeing wastewater treatment．In 20 1 4，the total discharge of textile dyeing sludge in China was 4．91 million tons f80％moisture content)．And the main disposal of the sludge was landfill and incineration．In addition，our previous study showed that polycyclic aromatic hydrocarbons(PAHs)， known to be toxic，mutative，carcinogenic and teratogenic to humans，were a type of recalcitrant organic pollutants in textile dyeing sludge．At some textile dyeing plants，the contamination level of PAHs in sludge has been reported to be as high as 1 6．7 mg／kg dry sludge．Therefore，it is necessary to remove the PAHs in textile dyeing sludge． In the present study，the PAHs in textile dyeing sludge w ere treated using a combined Fenton and ultrasound approach．The specific obj ectives were as follows：(1)to evaluate the kinetics coefficients and the synergistic effect between ultrasonic irradiation and the Fenton process for the degradation of PAHs in textile dyeing sludge．(2)To investigate the effects of various operating parameters on the degradation of PAHs during the US／Fenton process，such as ultrasonic density，reaction time，molar ratio of H202 to Fe2+，pH value and H202 dosage．And(3)to determine the interaction effects of different variables and obtain the optimal conditions using the central composite design(CCD)model for the treatment of PAHsin textile dyeing sludge．The main results of these studies could be summarized as follows． US combined with Fenton treatment could be more effective for the degradation of PAHs in textile dyeing sludge，which presents e