纺丝用PA662fSiO2纳米复合材料的制备.pdfVIP

Abstract Abstract Nylon 66 is one of the most widely used polymer materials as the tire cord which has high strength, good adhesion with rubber and other advantages. But now with the requirements of the automotive industry for tire performance becoming higher, the low modulus and thermal dimensional stability limit its application. This work aims to improve the modulus and dimensional stability of nylon 66 by the nano-composite modification technology. Using the in-situ polymerization method to ensure the good dispersion of nano-fillers, and the condensation product were processed by the solid phase polycondensation in order to achieve the spinning molecular weight requirements. The main results are as follows: (1) PA66/SiO2 nanocomposites was prepared by in situ polymerization ，the molecular weight is about 13000. Molecular weight of the product was very stable and the dispersion of nanoparticles was good. DSC results showed that nano-SiO2 played a good role in nucleating agent, which significantly improved the crystallinity and crystallization rate. At last, the mechanical properties of PA66 composites improved. 4 (2)The molecular weight of PA66 increased from about 1.30 ×10 to about 4 2.10 ×10 by solid phase polycondensation method which reached the spinning requirements. The reaction conditions were temperature 175