ppc型革用聚氨酯的合成及新多元醇的开发高分子化学与物理专业论文.docxVIP

广东工业大学硕士学位论文 广东工业大学硕士学位论文 会出现裂纹，由于时间关系，本文并未深入研究。 关键词：聚碳酸亚丙酯二元醇、皮革、皮革涂饰剂、二氧化碳、聚环己烯碳酸酯 V 万方数据 ABS ABS TRACT ABSTRACT Most of polyurethane leather is prepared舶m polyester or polyether．Polyester based polyurethane shows low hydrolysis resistance，and polyether based polyurethane exhib its remarkable hydrolysis resistance．However the films prepared fiom polyether show poor surface hardness and mechanical properties．Polyurethane derived from poly(propylene carbonate)diol(PPC)exhibits supe南r mechanical properties，friction resistance，and hydrolysis resistance due to multi-carbonate and ether linkages in the molecular chain． Polyurethane leather slurry fiom PPC as the waterbome polyurethane s(WPU)leather finishing agents Was prepared to improve—gidity of water-based resin surface．Poly- cyclohexene carbonate diol(PCHC)Was synthesized from carbon dioxide and cyclohexene， and the e位cts on polymerization rate were also investigated．The obtained results are listed as f0110WS： 1．PPC based polyurethane leather slurry with high molecules and viscosity was prepared by trifle NCO amount method under 80。C，and catalyst was added with the first addition stage of diphenyl methane diisocyanate． 2．Alkali resistance of PPC based polyurethane leather slurry was supe南r with comparing polybutylene adipate(PBA)based leather slurry,and slightly infe r ior compared with polytetrahydmfuran(PTMG)type leather slurry． 3．Compared with the PBA or PTMG waterborne leather finishing agents，the film fabricated form PPC showed poor glossine ss． 4．The enhanced properties(back-adhesive resistance，tensile strength，thermal resistance and solvent resistance、and redmed crystallinity of 1ilm were obtained by modifying with trimethylolpropane． 5．PPC based leather finish agent was modified with Y—aminopropyl triethoxysilane． The introducing of silane coupling agent improved the diameter and diameter distr弛utio n of the emulsion and surface hydrophobicity,however reduced the water absorption． 6．Poly(cy