硼砂交联低聚羟丙基塔拉胶可再生凝胶体系的制备-高校化学工程学报.PDF

第26 卷第5 期 高 校 化 学 工 程 学 报 No.5 Vol.26 2012 年10 月 Journal of Chemical Engineering of Chinese Universities Oct. 2012 文章编号：1003-9015(2012)05-0901-04 硼砂交联低聚羟丙基塔拉胶可再生凝胶体系的制备与流变性研究 朱广宇, 方 波 (华东理工大学 化学工程研究所 化工流变学研究室, 上海 200237) 摘 要：开发低成本可再生压裂液对油气田强化开采具有重要意义。今合成了低聚羟丙基塔拉胶，表征了双氧水对其 降解程度的影响，考察了低聚羟丙基塔拉胶浓度和硼砂浓度对凝胶形成的影响，得到了稳定的硼砂交联可再生凝胶体 系。考察了不同再生次数凝胶体系的流变性，结果表明再生3次以下的凝胶体系具有良好的黏弹性、触变性和剪切变稀 性，再生前后凝胶体系流变性无显著变化。该可再生凝胶体系的流变曲线可用非线性共转 Jeffreys 模型描述，实验值 与模拟值吻合良好。 关键词：低聚羟丙基塔拉胶；硼砂交联；可再生；黏弹性；触变性；剪切变稀性 中图分类号：O648.18 ；TQ427.26 ；O37 文献标识码：A The Preparation and Rheological Properties of Regeneratable Borax/Degrated Hydroxypropyl Tara Gum Gel Systems ZHU Guang-yu, FANG Bo (Research Laboratory of Chemical Engineering Rheology, Chemical Engineering Research Center, East China University of Science and Technology, Shanghai 200237, China) Abstract: It is important to develop regeneratable fracturing fluid with low cost for enhanced exploitation of oil-gas fields. In this paper, the Degrated Hydroxypropyl Tara Gum (DHPTG) was synthesized, and the influence of hydrogen peroxide dosage on its degradation degree was studied. The effects of DHPTG and borax concentrations on the formation of gel systems were investigated, and stable borax cross-linked DHPTG regeneratable gel systems were obtained. Furthermore, the rheological properties of the gel systems with different regeneration times were investigated. The results show that the gel systems with less than 3 regeneration times possess good visco-elasticity, thixotropy, and shear thinning properties, and the rheological propertie