发光碳纳米颗粒和cds量子点的合成表征及应用化学分析化学专业论文.docxVIP

反应的起始原料填充比例进行控制。由于碳纳米颗粒具有较大的比表面积，合成 反应的起始原料填充比例进行控制。由于碳纳米颗粒具有较大的比表面积，合成 的催化剂有比较高的催化效率。催化剂活性通过循环伏安法(Cyclic voltammetry， CV)和旋转电极伏安法(Rotating disc voltammetry，RDE)检测。 4．基于表面增强拉曼散射技术(SERS)，内壁修饰Ag纳米颗粒的中空导波 管被用作分子检测的传感器。在用内壁涂覆中空导波管检测R6G分子的过程中 发现，与单衬底传感器相比较，新构建的双衬底传感器具有较高的灵敏度。灵敏 度增强是由于双衬底传感器同时具有微空腔和“三明治”结构两种导致SELLS增强 的结构，比直接检测的灵敏度高两个数量级。 5．合成水溶性的CdS量子点，并且在量子点表面修饰聚乙烯亚胺高分子构建 检测Cu2+的传感器。修饰聚乙烯亚胺分子后的量子点发光强度为修饰前的两倍， 具有很高的灵敏度。 关键词：碳纳米颗粒；氧还原反应：光致发光；重金属离子；SERS；量子 点 Abstract‘Nanomaterils”refers Abstract ‘Nanomaterils”refers to materials谢t11 morphological features on the nanoscale， and especially those which have special properties stemming from their nanoscale dimensions．As the sizes of the materials are close to light wavelength and、Ⅳim hi曲 surface areas．a certain number of physical properties of the nanomaterials alter、)l，iⅡl the change from macroscopic systems，for examples，melting point,magnetic property, optical property，thermal and electron conduction．Carbon nanomaterials possess quite uinique phy7sical-chemical property and multiple forms，have been wildly used in areas such as biology,semiconduction，information and communication technology, medical and health．However,the synthesis of carbon nanaomaterials(1aser etching, plama irradiation,CVD )usually needs harsh condition,expensive equipments and consuming hi曲energy．This thesis discussed simple synthesis of luminescent carbon nanopartides from natural gas soot and further synthesized carbon／melzl nanocompostie as catalysts for oxygen reduction reaction． 1．Carbon nanoparticles were prepared by refluxing the combustion soot of natural gas in nitric acid．Transmission Electron Microscopy measurements showed that the resulting particles exhibited an average diameter of 4．8+0．6 nm,and the crystalline lattices were consistent with graphitic carbons．13CNMRand FTIR spectroscopic measurements further confirmed the presence of sp2 carbons in the form of aryl and carboxylic／carbonyl moieties．The resulting carbon nanoparticles