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無機物理方法（NMR部分）作業(共4次)
Assignment 01
1. Calculate the Larmor frequency of the following nuclei in a magnetic field of 4.7
Tesla:
Hydrogen-1, Carbon-13, Sodium-23, Phosporous-31, Rb-87, Platinum-195
2. Given that the NMR signal of a sample is 0.1 mV in a spectrometer with a
magnetic field of 4 T, what is the NMR signal of the sample in a magnetic field of 16
T, assuming that all other conditions are the same?
Assignment 02
1. Choose the correct one(s) from the following statements or explain briefly your
supporting reason if you decide that one is incorrect:
a. The resonance frequency of a given nuclear spin is solely determined by the
applied magnetic field for the resonance frequency is equal to γΒο.
b. Nyquist’ entative
e is used.
c. The narrower a signal is in the ti
domain.
d. ded by the
total acquisition time and the excitation pulse width.
2.Calculate the excitation width and effective excitation width of an RF pulse of (a)
20 ms, (b) 1ms, (c) 100µs, (e)10µs and (f) 2µs.
3. What is the spectral width covered by a digitizer operating with a dwelling time of
50 µs? What would it happen to a peak with resonance frequency of 55 kHz?
4. What causes baseline distortion?
5. What are the differences between a selective pulse and a non-selective one?
1
6. Explain the uses of window functions and zero-filling.
Assignment 03:
1. Which of the two chemically different types of protons in CH2ClCHCl resonate
2
2
at
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