电石法pvc生产中高沸物的回收利用化学工程专业论文.docxVIP

拟计算，在选用DNl6金属鲍尔环作为填料的前提下，确定精馏塔直径 拟计算，在选用DNl6金属鲍尔环作为填料的前提下，确定精馏塔直径 500mm，填料高度8米，等效塔板高度O．4米，理论塔板数20层，塔顶冷 凝温度控制在10．21℃，塔底再沸器控制在75．74。C，进料速度913．24kg／h， 进料位置距离塔顶5．6米，操作压力3．5atm。 通过运行后不断的优化操作流程及参数，前期分离出的二氯乙烷较为 清澈，后期颜色偏黄偏绿，但是成份并未发生变化，同时分离塔的上下阻 力有开车初期的6KPa，上涨至125KPa，分析为分离塔填料堵塞，后根据 生产周期及产品质量调整需要，定期更换堵塞填料。实现装置的长久平稳 运行。根据分析实验结果，塔顶氯乙烯采出纯度在95％左右，塔底二氯乙 烷采出纯度在85．92％之间。符合现有装置生产中对高沸物处理能力的需 求。 关键词：氯乙烯合成，高沸物，精馏，提纯。 万方数据 AbstractRecovery Abstract Recovery and utilization of high boiling substance in PVC production by calcium carbide method Abstract In the synthesis reaction of hydrogen chloride and acetylene，due to the characteristics of organic reactions，in addition to produce vinyl chloride，also generates dichloroethane，etc．，relative to vinyl chloride of high boiling point material，through the vinyl chloride rectification tower,after the separation of a restructuring are collectively referred to as’’the high boiling”，in the original process design，the¨high boiling¨as a kind of industrial by-product usually sold to manufacturers have an aptitude for dangerous waste treatment，then through the further production，processing and recycling．As countries of dangerous waste and environmental requirements higher and higher,the enterprise to the requirement of increasing the recycling economy,clean factory,all kinds of waste resources in the process of chemical production also is able to recycle．¨The high boiling’’this worth recycling of industrial by-product also be fully used． ’’The high boiling”consisting mainly of ethylene dichloride and vinyl chloride，including dichloroethane content is 40·5 0％，content of vinyl chloride in 50-60％．Dichloroethane for coatings，textile and other industries is 万方数据 万方数据 万方数据 北京化工大学专业硕士学位论文a 北京化工大学专业硕士学位论文 a kind of very good industrial solvent，has the very hi曲commercial potential， vinyl chloride is the production of PVC resin raw materials．The above both has the very high practical economic value．So”the high boiling’’purification proj ect，its economic benefits