型煤燃烧固硫中温度效应.PDFVIP

1998 1 ENVIRONMENTA L SCIENCE Jan. , 1998 * 林国珍　吕　欣　肖佩林 ( , 100085) FeSi , 2 . , , 1170 - 1220 , 10 , 1/ 4h ; 7 , , 1000 - 1300 , 50 , 1/ 2h . : FeSi , , , 1300 77% , 30% . X X , , . , , X , X . The Effect of Temperature on Efficiency of Sulfur Capture During Coal Briquette Combustion Lin GuozhenLu XinXiao Peilin ( Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085) , Abstract In this paper the effect of temperature on efficiency of sulfur capture w as studied for coal briquette w ith an additive( Fe, Si) at high temperature combustion. The results show ed that the coal briquette of Fe-Si system in process of combustion at different sampling conditions, the . rate of sulfur capture is obvious difference During the coal briquette entered into the furnace directly at 1300 , the rate of sulfur capture reached up to 77% . Characterization of the slags left after combustion has been carried out by using X-ray pow der diffraction method and X-ray fluorescent spectrometry . No other crystalline sulfur-containing species besides CaSO4 and CaS w ere found A vitreous iron oxides and small amounts of silicate w ere identified on the surface. of sulfur-containing grains by means of other method. T his might explain the diffusion barrier mechanism of sulfur fixation during coal briquette combustion at high temperature. , , - , - Keywords coal briquette sulfur capture X ray pow der diffraction method X ray fluorescent spectrometry . , , , . X 2