低温等离子体技术对玻璃离子粘固剂表面修饰的研究材料学专业论文.docxVIP

摘 摘 要 摘 要 本项研究运用低温等离子体技术(介质阻挡放电)对玻璃离子粘固剂中的玻璃粉体 进行了表面改性处理，等离子体的刻蚀作用使玻璃粉体表面的粗糙度增加，表面Ca2+等 阳离子浓度降低，并使其表面亲水性基团(硅羟基团)显著提高，改善了玻璃粉体的亲 水性能，提高了粘固剂的机械强度。 通过SEM表征了等离子体处理前后玻璃粉体表面形貌的变化、XPS表征了其表面羟 基含量的变化、运用FT-IR分析了等离子体处理前后的玻璃离子粘固剂表面结构的变化、 接触角的测定表征了其亲水性的改善。分析表明，经等离子体处理后，玻璃粉体表面的 形貌和性质发生了明显的变化。玻璃粉体亲水性的增强有利于与聚丙烯酸之间的反应， 从而提高玻璃离子粘固剂的机械强度。玻璃粉体表面Ca2+等阳离子浓度的降低是延长玻 璃离子粘固剂固化时间的直接原因。研究了介质阻挡放电(DBD)的处理工艺参数(如 处理电压、频率、极板间距、处理时间等)对玻璃粉体表面性质以及对粘固剂的机械强 度和固化时间的影Ⅱ向。并分析其影响因素，优化DBD处理工艺参数。 实验表明，利用介质阻挡放电(DBD)等离子体技术在常压均匀放电的条件下，完全 可以应用于粘固剂中玻璃粉体的表面改性，提高粘固剂的机械强度。 关键词：介质阻挡放电(DBD)等离子体，粘固剂，表面改性，亲水性能，固化时间 AbstractThis Abstract This paper studied surface modification of glass powder in Glass·ionomer Cement(GIC) by means of dielectric barrier discharges(DBD)，etch of plasma make coarse degree of glass powder increase，decrease the Ca2+consistence of surface and improve the hydrophilic property functional groups(Si—oz-0 obviously,ameliorate hydrophilic property of glass powder,improve the mechanical intensity of GIC． Surface topography、surface hydroxy group content、improvement of hydrophilic property on surface of glass powder pretreatead and treatead by plasma were characterized by SEM， XPS，Contact angle analysis．Surface structure of GIC were characterized by FT-IR．The results show that plasma causes surface topography and character of glass powder changed． Hydrophilic property improvement is due to surface roughness and introduction of hydroxy group．The improvement of hydrophilic proerty is benifit to the reaction of glass powder and poly．acrylate．The reason of the setting time of GIC iS extended because Ca计concentration of glass powder surface decline，improve the mechanical intensity of GIC．Study the effect of surface character of glass powder and the mechanical intensity and solidify time of GIC by the treatment conditions(voltage，frequency,gas discharge gap distance and time)of DBD． Analysis influence factor，optimize the treatment conditions of DBD． The results show that the surface modification of glass powder