粉煤灰基无机絮凝剂的分析矿产普查与勘探专业论文.docxVIP

摘 摘 要 废物资源化利用是经济可持续发展和环境生态保护的重要途径之一，本论 文以七台河电厂燃烧排出的固体废弃物粉煤灰为研究对象，通过对其化学组分 分析可知，粉煤灰中A1：0。的含量为20．60％，Si0：的含量为67．32％，Fe：0。的含 量为3．84％，具备元素提出并制备聚合硅酸铝铁的条件。本论文添加助溶剂以 热活化形式来打开Si—A1键，并用铝的浸出率作为评价指标分析活化结果，确 定了最佳活化条件。通过正交实验确定了使铁、铝达到最高浸出率工艺条件， 使铝、铁的浸出率达96％。设计正交试验确定了使硅达到最高浸出率的工艺条 件，使硅的浸出率达到75％。利用实验所获取的铝、硅、铁的溶液并用三氯化 铁补充一定量的铁为原料，设计正交试验制备聚合硅酸铝铁絮凝剂，结果表明： 制备絮凝剂的pH值为3，熟化温度为60℃，熟化时间为2小时，Si：(Al+Fe) 为1：1，A1和Fe的摩尔比为1：O．5时制各条件较佳。通过煤泥水的絮凝实验 表明：温度为30℃，pH值为9，搅拌强度50r／min，搅拌时间2min及絮凝剂 用量为1500mg／L时，剩余浊度为68NTU，且絮团粗大，沉降速度较快，沉积物 体积较小，絮凝效果优于市售的聚合氯化铝絮凝剂。 关键词粉煤灰；无机絮凝剂；聚硅酸铝铁；煤泥水 AbStraCtUtilization AbStraCt Utilization of reclanlation waStes is aIl importa芏lt means for me sus嘶nable development of the economy aIld the protection of the ec0109ical enViro衄em．In the t11esis，廿le Stlmy of solid excreto巧product，fly ash，exhausted f如m a thermal power plault in Qitaihe．By aIl甜yzing t：he chemical elements，its A1203 coment is 20．60 percent，its Si02 content is 67．32 percent and its Fe203 content is 3．84 percent，wllich haVing me condition t0 extract those虹nds of elements and to prepare PAFSi by adopting tecllnology of hydrotropy a11d technology of acid leaclling．This mesis added cosolvent to thennal activation fo皿to open the Si—Al bond，and aluminum in the leacmng rate of actiVation嬲a result of eval嘣ion．This test dete肌ined optimal activate roasting e仃’ect．Throu曲orthogonal expe曲ems I determined the llighest leaclling rate conditions of iron觚d alum№．T11ey made aluminum a11d iron leaclling ratc of 96 percent．By onhogonm experimem to determine t_he higheSt leac王ling rate of silicon process cond“ionS．They made tIle leaching of silicon rate of 75 perCent．Using the aluminum，silicon aIld iron丘om也e experiment 锄d adding a certain amoum of iron 埘th FeCl3 aus豫w materials，desigIled orthogonal fIerric silicate polymer prep锄tion，the results showed that：the beSt preparation conditionS、vere the pH Value is 3，the curing temperanme is 60℃，the cu血g tiIlle is 2 hours，Si／(Al+Fe)for the 1：l and Al，FeⅡlolar ratio of l：0．5n玳)u曲t：he slime f