废旧布袋活性炭的制备及其在印染废水深度处理研究环境科学与工程专业论文.docxVIP

广东工业大学硕士学位论文散为主，当时间大于10 广东工业大学硕士学位论文 散为主，当时间大于10 min时，则以膜扩散和内扩散为主。 利用WFBAC对印染废水进行深度处理，考察了吸附时间、WFBAC用量和吸 附温度对印染废水尾水CODcr和TOC去除的影响；同时对印染废水中CODcr的吸 附动力学进行了研究。结果表明：当吸附时间2 h、WFBAC用量1．0 g／L、吸附温度 为30 oC时，CODcr和TOC的去除率分别达到77％和74％，比同等条件下CAC 对印染废水尾水CODcr去除率高24．19％。WFBAC对CODcr的吸附符合准二级动 力学方程(R20．991。吸附速率在前30 min由颗粒内扩散主导，30 min之后则以膜 扩散为主。 关键词：废旧除尘布袋；活性炭；苯胺；吸附；动力学；热力学 万方数据 ABSTRACTABSTRACT ABSTRACT ABSTRACT Waste filter bags(WFBs)are one of the fastest growing industrial wastes in china， The raw material of WFBs mainly consists of synthetic chemical fibers-which high in carbon and have poor in biodegradabi lity—that is most important to prepare activated carbon(AC)．AC adsorption is one of the most widely used processes due to its simple operation and methodology．Dyeing wastewater must be treated by physical、chemical and biological method to satisfy the emission control regulations．In this paper，WFBs was used to prepare AC，and advanced treatment on dyeing Wastewater．Aniline on WFBAC were determined from batch tests，the efficiency of the activated carbon prepared from waste filter bags(WFBAC)was compared with that of the commercial activated carbon(CAC)in this study The WFBs used for the preparation of AC were obtained from the manufacturing processes in fumiture plant in Dongguan City，Guangdong Province，China．The elemental analysis and the proximate analysis of WFBs shown that the volatiles of WFBs Was high to 87．57％，C％was 62．2％and the fix carbon Was 9．55％。 WFBs were used as precursor for AC preparation by chemical activation．The effects of activation parameters(temperature，heating rate and NaOH：chars impregnation rate)，carbonization time and activated agent(NaOH，ZnCl2 and H3P04)on the performance of AC adsorption removal of aniline from aqueous solution were selected tO investigate．2 h of carbonization time、1：2 of chars impregnation rate、600。C of activation temperature、8。C／min of activated rate and chemical activated by NaOH was obtained that more suitable for aniline uptake．The