淀粉改性水煤浆分散剂的制备及其应用性能研究化学专业论文.docxVIP

67％，表观黏度为906mPa·s：浆体具明显的剪切变稀流动特性；OSSA的 67％，表观黏度为906mPa·s：浆体具明显的剪切变稀流动特性；OSSA的 吸附模型为单层吸附，饱和吸附量为4．35mg／g：浆体的稳定性高。 以苄基氯为疏水化试剂，异丙醇和水的混合溶液为溶剂，羟乙基淀粉 及氧化淀粉为主链，分别合成了苄基氧化淀粉(BOS)及苄基羟乙基淀粉 (BHS)水煤浆分散剂。通过FT-IR、1H-NMR对其结构进行了表征和分析， 通过热重分析仪(TA)对产物的热力学性能进行了测试。将两种分散剂应 用于神华煤制浆，考察分散剂最佳用量及最大成浆浓度，并对浆体流变性、 稳定性，分散机理等进行了研究。结果表明，相较于BHS，BOS的应用性 能较佳；BOS的最佳添加量为0．5％，最大成浆浓度为65％，表观黏度为 754 mPa·s；放置7天后析水率为3．35％。 关键词：水煤浆，淀粉，磺化，降解方式，苄基化 Ⅱ 万方数据 STUDY STUDY oN PREPA R ATION AND APPLICATIoN OF STARCH MODIFIED COALⅥ给TER SLUIU≤Y ABSTRACT China is one of the world’S coal producing superpowers，but the comprehensive utilization of coal resources is not high．the environmental pollution problem caused by coal combustion iS increasingly serious at the same time．Therefore，how to efficient and environmentally friendly utilization of coal resources has aroused the attention of the experts and scholars．As a new generation of clean oil combustion and its high combustion rate and convenient transportation，Coal water slurry has attached great attention of the personage inside．Dispersant Was an indispensable and important additive to the preparation of high concentration and low viscosity of coal water slurry,as the key factors which affected the performance and price of coal water slurry．The main function of it Was to improve the pulp concentration and reduce the apparent viscosity of coal water slurry,while the stability of coal water slurry Was enhanced．Starch reserveed abundantly in the nature，its characteristics of low cost，environmental protection and renewable had gradually become one potential research direction in the field of coal water slurry(CWS)． Starch dispersant of coal water slurry Was obtained by natural polymer modified starch，with the advantages of a wide range of sources，green environmental protection，high pulping stability etc．However,existing research Was only limited to graft copolyrnerization and partial primary modification of starch．Although the铲m copolymer of starch had good dispersing effec