半导体纳米晶的制备及其在聚合物太阳电池中的应用研究材料学专业论文.docxVIP

AbstractSolar Abstract Solar energy is a kind of inexhaustible clean energy,the appropriate exploitation of it Can greatly alleviate the energy crisis which man is facing nOW．Conjugated polymer photovoltaic devices have attracted great attention in recent years due to their low-cost,simple manufacture process，the potential for lage-area and the possibility to realize it in flexible substrate．Although the energy conversion efficiency(ECE)of polymer photovoltaic devices reached 5％at these days．it needs to be further improved for commercial applications．One of the reasous for the low ECE in polymer photovoltaic devices come from the low mobility of carriers(electrons and holes)in polymers，and another is that the spectral response of the conjugated polymer is mismatching with solar-terrestrial radiation．The introduction of inorganic semiconductor nanocrystals 0VCs)、Ⅳith higher electron affinity and good cartier mobility(such as CdS，CdSe,ZnO，Ti02，OaAs)may enhance the charge separation and transport，and then lead to the improvement ofdevice performance．Photovoltaic devices from the NCs／conjugated polymer composite have attracted great research interest in recent years due to their combination ofthe easily proeessibility and flexibility ofpolymers and the higher carrier mobility and surface to volume ratios of inorganic NCs．The utilization of semiconductor NCs aS the acceptor phase in composite photovoltaic devices has grown aS an important branch ofthe technical research ofsemiconductor NCs． This thesis is concentrated on the new synthetic routes of semiconducting CdS，CdSe and CdTe NCs and their application aS acceptor phase in polymer heterojunction solar ceils．We prepared CdS nanorods and multi—armed nanorods via thermolysing single precursor in higII boiling point solvent．The reaction temperature．precursor concentration and reaction time Can significantly influence the size，morphology and crystallinity of CdS NCs．The photoluminescence of MEH—PPV is increaSingly que