典型农业区中阿特拉津的污染识别与风险评估环境工程专业论文.docxVIP

典型农业区中阿特拉津的污染识别与风险评估采用危害商值法(HQs)评估ATZ及其氯代产物的环境生态风险。结果显示，除章党 典型农业区中阿特拉津的污染识别与风险评估 采用危害商值法(HQs)评估ATZ及其氯代产物的环境生态风险。结果显示，除章党 铁路桥用药后四个月外，其他所有点整个时期HQ值(绿藻)均远远大于l，表明环境水 体中ATZ及其氯代产物在整个时期内对绿藻产生极大的生态风险。在整个采样时期内， 残留浓度C0．1 gg／L的占98．6％，表明对蛙类的内分泌系统和生殖系统产生了严重的 影响和危害。通过生态风险评估，筛选出社河流域的腰堡水库、苏子河流域的古楼大桥， 以及浑河支流的章党铁路桥等高生态风险采样点，结合污染来源分析及降解实验，对高 风险样点提出阻隔农田污染输入和沉积物污染修复等建议。 关键词：阿特拉津；代谢产物；土壤降解；残留分析；风险评估 万方数据 Contamination Contamination Identification and Risk Assessment of Atrazine in Typical Agricultural Region Ab stract Atrazine iS one of the triazine herbicides．It iS widely used to controI grassy and broadleaf weeds in corn，sorghum and other plants．One of the main environmental problems about the use of atrazine iS its persistence．This herbicide iS considered all endocrine disrupting chemical．Even worse，dealkylation products of atrazine，atrazine．desethyl(DEA) and Atrazine-deisopropyl(DIA)，appear similar toxicity to the parent herbicide．The hydrolysis of ATZ metabolites(OHA)may lead to kidney stones and nephritis．The ecological risk of atrazine brought more and more attention。 In this study，we established some methods with the combination of QuEChERS．SPE． HPLC and HPLC-MS／MS for the analysis of atrazine and its metabolites．Firstly．the degradation processes of ATZ in five soils were studied，and then compared with the degradation activity of ATZ in different soils according to the first order kinetics．Secondly． we analyzed the residual concentrations of ATZ and its metabolites in water．soll and sediment samples in typical agricultural region．In addition，we analyzed the relationship of ATZ and its metabolites between time，space and muff—media in the environment．Finally，the toxicity data of ATZ were collected to assess the ecological risk of ATZ and its chlorinated metabolites in the typical agricultural rigion by hazard quotient method． The results showed that the degradation rate constant of k of atrazine in unsterilized soils： kfarmltindA2(0，404 d1)是缸。1andAl(0．339 d‘1)k。“O，282 d-J)kpond(0