磁性微纳米材料的混合溶剂热制备表征与性质研究无机化学专业论文.docxVIP

ABSTRACTABSTRACT ABSTRACT ABSTRACT Two parts of researches were dones in the work．First，Fe304 hollow microsphere chains was synthesised in glycerol—water mixed solvent system．Fe304 octahedral chains can be formed with changing the pH value，and the magnetic properties of these two chains were studied．Second，a—Fe203 porous structures were synthesised in mixed solvent system consisted of THF—water．A contrastive study was made on the surface area ofthem．The main points list as follows： 1．Fe304 hollow microsphere chains with length of 8—1 1 lam have been solvothermally synthesized in the mixed solution of glycerol and water with 1 M NaOH．The hollow microspheres are O．7-1 Ixm in diameters and the thickness of the shells is 1 50·300 nm．The shell of the hollow microspheres is constructed by octahedrons of 1 00·1 70 nm．However,when the concentration of NaOH is adjusted to 3 M，the octahedron chains with length of 30—50 pm be obtained．The magnetic smuration values of hollow microsphere chains and octahedron chains are 88。1 and 1 02．4 emu／g at room temperature，respectively． 2。a—Fe203 porous structure was successfully synthesised by mixed solvent systems consisted of THF—water．The porous microcube morphology had a distinctive feature． The crack growth trend is found in the particles on the edge during the synthesis procedure，and has a larger hole density than that ofthe 12 surfaces．The samples were characterized using XRD，TEM，SEM，etc。The surface area properties were studied．At last，magnetic properties ofporous microcubes were measured at 300 k and 5 K，respectively． Keywords：Fe304，a-Fe203，chain structure，porous structure，magnetic properties． II 论文原刨性和授权使用说明中国科学技术大学学位论文原创性声明 论文原刨性和授权使用说明 中国科学技术大学学位论文原创性声明 本人声明所呈交的学位论文，是本人在导师指导下进行研究工作所取得的成 果。除已特别加以标注和致谢的地方外，论文中不包含任何他人已经发表或撰写 过的研究成果。与我一同工作的同志对本研究所做的贡献均已在论文中作了明确 的说明。 作者签名： 签字日期：沪丝：￡：』孕 中国科学技术大学学位论文授权使用声明 作为申请学位的条件之一，学位论文著作权拥有者授权中国科学技术大学拥 有学位论文的部分使用权，即：学校有权按有关规定向国家有关部门或机构送交 论文的复印件和电子版，允许论文被查阅和借阅，可以将学位论文编入有关数据 库进行检索，可以采用影印、缩印或扫描等复制手