超导材料mgb2的燃烧合成及结构转变研究材料学专业论文.docxVIP

硕士学位论文Abstract 硕士学位论文 Abstract Combustion symhesis method shows its ullique advantage in preparation for MgB2 superconductor Howevcr the I(Ilowledge of the reaction pmcess aJld mechanism during combustion is extremely limited because of the unique Mg—B system and the rapid reaction process aIld hi曲synthesis temperature So the research on the mechanism of self-propagating combustion syhthesis’MgB2 has its importam significance in both the perfection of the combustion method itself and e耐ensiVe 印plication ofMgB2 In this papeL a reIatively general research on the weak exothermic reaction system of MgB2 has been made厅om thermodynamics and structure dynamics The relationships among the preheat temperature aIld adiabatic temperature are definite thmugh the calculation of adiabatic temperature under ideal state． The pure ime加etalljc MgB2 are syhthesis by self．propagating combustion mode and themal explosion mode respectively，between which a comp捌son ofthe reaction process has been made，and the di疏rent technical demands are definite The e髓ct of di疏rem technical parameters in preparation for MgB2 during themal eXplosion reaction mode on the phase compose and morphology of product has been studied， these parameters include preheat temperature， preheating Velocity’ temperature hoIding time，pressure，Mg gra叫larity and djluent On this basis，an optimaltechnical paramcters scheme of combustion symhesis MgB2 has been summed up． The mechanism of themal explosion synthesis in MgB2 could be described with a melt afld dissoIution—precipitation mold．The reaction between Mg and B particles started with the melting Mg． A mrther experimem of Combustion Front Quenching(CFQ)was brou曲t to success in cylindricaI steel mould by adding some A1一Ti—C powde‘which is accepted hi曲exothemic system on the top of M哥B samples The physical and chemical changes of all regions in the quenched samples during the combustion symhesis were followed by scanning electron microscopy(SEM)，energy—dispersiVe spect