氟化碳材料制备及其锂电池应用研究材料学专业论文.docxVIP

摘要本文以氟化石墨(fluorinated 摘要 本文以氟化石墨(fluorinated graphite，F．Graphite)作为锂电池正极材料的活 性物质，将其组装成扣式电池并测试了其恒流放电性能。在0．1 mA cm。2小电流 密度放电时其具有高的比容量(800 mAh／g)，比能量(1883 mWh／g)和工作电 压平台(2．65 V)等。但在1C高倍率放电时氟化石墨锂电池综合性能明显下降。 同时开展了提高氟化石墨锂电池在大倍率放电情况下放电性能的研究。首 先，采用多壁碳管(multi-walled carbon nanotubes，MwCNT)作为导电剂材料可 ≮ 以明显提高电池倍率性能，并提出了导电剂选择原则。另外采用物理掺杂方法， 如掺入金属氧化物、金属、导电聚合物等。最后通过测试电池在不同的温度下的 岫 放电性能，发现其在20℃～60℃时电池比容量和电压平台均有很大提升，且提 出电解液选择原则。 采用高温气相法合成了氟化多壁碳管(fluorinated multi．walled carbon nanotubes，F．MwCNT)将其作为锂电池正极并组装成扣式电池，测试不同倍率 放电性能，发现与氟化石墨锂电池相比其在0．1C—lC倍率放电时均具有更高的 比容量、比能量以及电压平台等。 最后对导电剂选择为多壁碳管提升电池综合性能进行了相关的理论分析，讨 论了氟化碳管的氟碳比与碳管结构破坏程度的内在联系，理论计算出锂离子在氟 化多壁碳管中的扩散系数要大于氟化石墨。 关键词：多壁碳纳米管氟化锂电池倍率性能 ～ ∥ ABSTRACTIn ABSTRACT In this paper，fluorinated graphite(F-Graphite)was chose as the active material of lithium batteries’cathode material．Coin-type lithium batteries were prepared and their discharge performance were tested，which exhibited high specific capacity (800 mAh／g)，high specific energy(1 883 mWh／g)and high working voltage(2．65 V) at O．1 mA cm～current density．HoweveL the discharge performance of F—Graphite lithium batteries went down remarkably at I C rate． Meanwhile，different methods to improve the discharge performance of F．Graphite lithium batteries were carried out．The multi-walled carbon nanotubes OVlWCNTs)were chose as conductive agent，which could improve rate performance of lithium batteries remarkably．The metal，metal oxide，conductive polymer was doped into F-Graphite，which also could change the discharge performance of lithium batteries to some extent．The proposal of operating guide of electrolyte was pointed out by testing the discharge performance of lithium batteries，which exhibited hiigh specific capacity and working voltage at the temperature range of 20。C-60℃． The fluorinated multi—walled carbon nanotubes(F—MWCNT)using high temperature gas methods were prepared．The discharge performance of F-MWCNT lithium batteries were tested，showing the larger specific capacity and higher working v