马来酰亚胺型聚羧酸系减水剂大单体的制备-中国建筑材料联合会.PDF

第43 卷第5 期 硅 酸 盐 学 报 Vol. 43 ，No. 5 2 0 1 5 年 5 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY May ，2015 DOI ：10.14062/j.issn.0454-5648.2015.05.07 马来酰亚胺型聚羧酸系减水剂大单体的制备 李继新，王海玥，蒋 锋，李志丹 (沈阳工业大学石油化工学院，辽宁 辽阳 111003) 摘 要：以N-氨基甲酰马来酰亚胺(NCM)和氯代聚乙二醇单甲醚(CMPEG)为单体，在氢氧化钠作用下，合成N- 聚乙二醇单 甲醚-N’-氨基甲酰马来酰亚胺(MPNCM)减水剂大单体，并对MPNCM 的结构进行表征。以净浆流动度和反应转化率为指标， 考察了 NCM/CMPEG 摩尔比、引发剂用量、反应温度和反应时间等因素对净浆流动度和反应转化率的影响。结果表明： NCM/CMPEG 摩尔比为1.2、引发剂用量(质量分数，下同)为0.8%、45 ℃反应4 h 所制的大单体的分散性能较为适宜。以最 佳反应条件制得的MPNCM 与丙烯酸(AA)为原料，共聚合成聚羧酸系减水剂，并对聚羧酸系减水剂的减水性能和分散性能进 行检测。结果表明：当聚羧酸系减水剂掺量为0.2%时，减水率达25.7% ，混凝土净浆流动度为315 mm 。 关键词：N-氨基甲酰马来酰亚胺；N- 聚乙二醇单甲醚-N’-氨基甲酰马来酰亚胺；聚羧酸系减水剂 中图分类号：O632.6 文献标志码：A 文章编号：0454–5648(2015)05–0594–05 网络出版时间： 网络出版地址： Preparation of Macromer for Maleimide-Structural Polycarboxylate Based Superplasticizer LI Jixin , WANG Haiyue, JIANG Feng , LI Zhidan (School of Petrochemical Engineering, Shenyang University of Technology, Liaoning 111003, China) ’ Abstract: N-methoxypolyethylene glycols-N -carbamoyl maleimide (MPNCM) was prepared with chlorophthalic methoxypolyethylene glycols(CMPEG), N-carbamoyl maleimide (NCM) and sodium hydroxide as a catalyst. The molecular structure of MPNCM was characterized. Effects of n(NCM)/n(CMPEG)(in mole ratio), degree of initiator, reaction temperature and reaction time on the conversion ratio and initial fluidity as a measurement index were investigated . The result shows that the optimal MPNCM can be obtained at the n(NCM)/n(CMPEG) ratio of 1.2, the amount of initiators of 0.8% (mass fraction, the same below) based on the mass of CMPEG and NCM, the reaction tem