磁性微胶囊的制备及其在酚类物质去除检测方面的应用-化学分析化学专业论文.docxVIP

2010兰州大学硕士学位论尹娟娟Abstract 2010兰州大学硕士学位论尹娟娟 Abstract Phenolic wastewater is one of the representative wastewater,which is difficult to treat in industry．This dissertation reviews the methods of phenolic wastewater treatment，the phenolic wastewater detection and present problems in detail，and then propose the topics of this dissertation．The following major innovation works were carried out based Oil the previous literatures： 1)Magnetic microcapsules containing tributyl phosphate(TBP)have been prepared successfully谢Ⅱ1 a phase inversion method,and the adsorption of phenols from aqueous solution using TBP／Fe304@PSF(polysulfone)microcapsules has been studied．The results showed that it took about 30 rain to reach extraction equilibrium wim most of phenols being adsorbed within the first five minutes．The investigation of potential industrial application provided encouraging results for the application of these magnetic microcapsules to the adsorption of phenols from aqueous solutions in large—scale operations． 2) Magnetic organic modified montmorillonite(OMMT)／Fe304@!PSF microcapsules and C 1 8／Fe304@PSF microcapsules were synthesized,the materials wore applied for cleanup and enrichment of 4-CP and 2-CP．Comparative studies wele carried out between OMMT／Fe304@PSF microcapsules and C1 8／Fe304@PSF microcapsules． Either adsorption or absorption rate， OMMT／Fe304@PSF microcapsules are superior to C1 8／Fe304@PSF mieroeapsules．So，we chose OMMT／Fe304@PSF microcapsules as magnetic solid phase extraction,established the measure method of 4-CP and 2-CP enrichment by magnetic solid phase extraction (MSPE)from water followed by HPLC determination．The experimental results showed that the established methods met the requirements of water quality analysis． Three parts are included in the dissertation Chapter I：Review of the phenolic compounds in water pollution,and the H 2010兰州大学硕士学位论尹娟娟commonly 2010兰州大学硕士学位论尹娟娟 commonly used phenolic wastewater treatment and detection,and then proposed to