蒽端基聚对苯亚乙炔的发光性能.pdfVIP

2002 年第 60 卷 化 学 学 报 Vol. 60 , 2002 第 6 期 , 1139～1143 ACTA CHIMICA SINICA No. 6 , 1139 ～1143 ·研 究 简 报 · 蒽端基聚对苯亚乙炔的发光性能 ① 牛俊峰 　　杨慕杰 　　孙景志 (浙江大学材料化工学院　杭州 310027) 摘要 　报道了一种新的蒽端基聚对苯亚乙炔的合成与发光特性 ,分别考察了聚合物 P2 的紫外吸收 ,荧光发射和电 致发光光谱. 结果表明 ,在聚对苯亚乙炔主链末端引入蒽基团可改变其有效共轭长度及发光颜色 ,合成的模型小分 子可证明这一点. 电致发光器件 ITOP2Al 在 600 nm 处发红光. 关键词 　聚对苯亚乙炔 ,蒽 , 电致发光 Luminescence Property of Anthracenecapped Poly ( pphenyleneethynylene) NIU , JunFeng 　　YANG, MuJie 　　SUN , JingZhi ( ) Department of Polymer Science and Engineering , Zhejiang University , Hangzhou 31002 7 Abstract 　The synthesis and luminescent properties of a new , solutionprocessable conjugated polymer ( P2) which was endcapped by anthracene were reported. The absorption , emission and electroluminescence ( EL) spectra have been investigated respectively. The results indicated that the endcapped group of anthracene can obviously influence the energy band gap of the corresponding polymer ( P1) . The results were further confirmed by spectroscopic comparison with the model compounds. EL in the red region of the spectrum with a maximum at 600 nm was observed from the polymer film sandwiched between indiumtinoxide and Al electrodes. Keywords 　poly ( pphenyleneethynylene) , anthracene , electroluminescence ( EL) 　　有机聚合物的电子结构和发光性质最根本决 动电压很高 ,约 100 V 才获得有效光输出 ,光电能量