反应工程基础（程易）chpt11catalysiscatalyticreactors.pptVIP

* * Ru: 钌 * * * * * * * 中文版书中KA应为kA * * * * * * There is a rate-limiting step, e.g. surface reaction, There is no rate-limiting step, * Isomerization of n-pentene (N) to i-pentene (I) over alumina Solving for CN?S and CI?S: * For surface reaction-limited mechanism: This rate law is identical to the one derived assuming that rAD/kAD?0 and rD/kAD?0 Site balance: * 10.3.7 Temperature dependence of the rate law Consider a surface-reaction-limited irreversible istlmerization The adsorption is exothermic. Consequently, the higher the temperature, the smaller the adsorption equilibrium constant. At high temperatures, * 10.4 Heterogeneous data analysis for reactor design Developing a algebraic rate law consistent with experimental observations Analyzing the rate law in such a manner that the rate law parameters can be readily be extracted from the experimental data Finding a mechanism and rate-limiting step consistent with the experimental data Designing a catalytic reactor to achieve a specified conversion. * Example * 10.4.1 Deducing a rate law from the experimental data Dependence on the product methane little effect?no/weak adsorption Dependence on the product benzene decreases with pB?adsorption Dependence on toluene increases with PT at low pressure, and is independent on PT at high pressure, ?adsorption, surface reaction Dependence on hydrogen Increases linearly with PH2?surface reaction, no/weak adsorption * 10.4.2 Finding a mechanism consistent with experimental observations For surface reaction-limited mechanism: For surface-reaction-limited mechanisms * Site balance: * 10.4.3 Evaluation of the rate law parameters Evaluate the rate law parameters, k, KT, and KB. Rearrange our rate law to obtain a linear relationship between our measured variables. One can use the linearized least-squares analysis to obtain initial estimates of the parameters k, KT, KB, in order to obtain convergence in nonlinear regression. However, in many cases it is possible to use a nonlinear