超高效液相色谱串联质谱法测定土壤中雌酮-食品安全质量检测学报.PDF

7 2 Vol. 7 No. 2 2016 2 Journal of Food Safety and Quality Feb. , 2016 马 帅, 冯晓元, 韩 平, 戴 莹, 平 华, 李 杨, 王纪华* (, (), , 100097) 摘 要: 目的 (UPLC-MS/MS) 方法 PSA+C18 , UPLC-MS/MS (MRM) , /(50:50, V:V)0.1% 结果 1~200 µg/kg , (r2)0.9974, (S/N=3)0.00120.0036 0.0058 µg/kg 1050 500 µg/kg 3 82.9~103.6%, RSD 7.7结论 , 关键词: ; ; ; ; ; Determination of estrone, 17β-estradiol and 17α-ethinylestradiol in soil by ultra-high performance liquid chromatography-tandem mass spectrometry with dispersive solid phase extraction MA Shuai, FENG Xiao-Yuan, HAN Ping, DAI Ying, PING Hua, * LI Yang, WANG Ji-Hua (Beijing Research Center for Agricultural Standards and Testing, Risk Assessment Lab for Agro-products (Beijing), Ministry of Agriculture , Beijing Municipal Key Laboratory of Agriculture Environment Monitoring , Beijing 100097, China) ABSTRACT: Objective To establish a method for the determination of estrone, 17β-estradiol and 17α-ethinylestradiol in soil by ultra-high performance liquid chromatography-tandemmass spectrometry (UPLC-MS/MS). Method According to dispersive solid phase extraction method, the soil samples were extracted by acetonitrile, pur