基于探针气体吸附等温线的矿物材料表征技术Ⅱ多孔材料的孔隙结构.PDF

基于探针气体吸附等温线的矿物材料表征技术： Ⅱ．多孔材料的孔隙结构 杨 侃1，陆现彩1，刘显东1，侯庆锋2 南京大学地球科学系 内生金属矿床成矿机制研究国家重点实验室 摘 要：含纳米孔的天然矿物岩石材料的吸附和催化性能对于表生地球化学过程、材料加工、应用及煤炭开发利用等方面均 有着重要意义。本文对比分析了各种纳米孔表征技术，重点介绍了基于吸附等温线的纳米孔研究方法。对三个典型样品等 温线数据的模型计算表明，应根据材料中孔的形态 平（行板状孔、球形孔和圆柱形孔）选择模型，不同类型孔所对应的计算方 法和参数有很大差别。表征材料表面能量均匀的样品可首先考虑采用DFT法；HK法一般只作为定性研究方法，BJH方法受 样品本身性质参数的影响较小，且计算简单，可广泛应用于介孔材料的孔径分布的表征。 关 键 词：孔隙结构；矿物材料；表征；探针气体吸附等温线 中图分类号：TB383 文献标识码：A 文章编号：1007-2802(2006)04-0362-07 CharacterizationTechniqueI[ofMineralMaterialBasedonProbeGasAdsorptionIsotherm : Nano-poreStructureofPorousMaterial YANGKan,LUXian-cai,LIU Xian-dong,HOU Qing-feng2 1.DepartmentofEarthSciences,NanjingUniversity,Nanjing210093,China;2.ResearchInstituteofPetroleum ExplorationandDevelopmentEORDepartment,Beijing100083,China Abstract:Thecharacteristicsofadsorptionandcatalysisofthenano-poresbearingnaturalrocksandmineralsplay ansignificantroleinthefieldsofsurfacegeochemicalprocess,coaldevelopmentandapplication,materialprocess- ingandapplication.Variouskindsoftechniquesforcharacterizingnano-porehavebeencomparedandanalyzedin thispaper.Especially,thispaperhasintroducedthenano-poreresearchmethodbasedontheadsorptionisotherm. Thecomputationresultsofadsorptionisothermalmodelsforthreetypicalsamplesindicatethatitisveryimportant toselectrighttypeofmodelbasedontheshapesofmajorpores(slitpore,sphereporeorcylinderpore)inmateri- als,becausethecomputationmethodsandparametersofvariousmodelscorrespondingtodifferentporetypesare quitedifferent.Whenthesurfaceenergyofthesampleisrelativelyeven,theDFTmethodisagoodchoice.The HKmethodisusuallyusedforqualitativeanalysis.TheBJH methodcouldbewidelyusedtocomputethecharac- teristicsofthemesoporesizedistributionasitisrelativelysmallinfluencedbythepropertyparametersofthesam- pleswithsimplecomputationprocess. Keywords:porestructure;mineralmaterial;characterization;