支化丙烯酸酯乳液制备和性能.PDFVIP

包 装 工 程 第 37 卷 第 11 期 ·42 · PACKAGING ENGINEERING 2016 年 6 月 支化丙烯酸酯乳液的制备和性能 于洋 1, 2 ，李斌 1 ，王鹏 1 ，辛秀兰 1, 2 ，徐宝财 1, 2 ，吴涛 1 ，禹晓燕 1 （1.北京工商大学，北京 100048 ；2.食品添加剂与配料北京高校工程研究中心，北京 100048 ） 摘要： 目的 研究支化单体对丙烯酸酯乳液的影响。方法 以顺丁烯二酸酐和季戊四醇为原料，通过酯 化反应制备聚酯型四臂支化单体，将其水分散液与甲基丙烯酸甲酯等单体进行乳液聚合，得到支化丙 烯酸酯乳液。测定不同比例分散液对乳液基本性能的影响。结果 制备乳液粒径分布 100~200 nm ，表 面张力稳定在 30~35 mN/m，增加分散液的比例可适当降低乳液粘度，降低吸水率。结论 将支化聚合 物引入乳液聚合体系，可有效降低乳液粘度和吸水率。 关键词：支化单体；聚丙烯酸酯；支化乳液 中图分类号：TS802.3 文献标识码：A 文章编号：1001-3563(2016)11-0042-05 Synthesis and Properties of Branched Polyacrylate Emulsion 1,2 1 1 1,2 1,2 1 1 YU Yang , LI Bin , WANG Peng , XIN Xiu -lan , XU Bao -cai , WU Tao , YU Xiao-yan (1.Beijing Technology and Business University, Beijing 100048, China; 2.Beijing Higher Institution Engineering Research Center of Food Additives and Ingredients, Beijing 100048, China) ABSTRACT: This work aimed to study the effects of branched monomer on the polyacrylate emulsion. A branched polymer (HBP4) was synthesized by esterification using maleic anhydride and pentaerythrite. And then it was neutralized with ammonia water. And the emulsion was synthesized by emulsion polymerization using methyl methacrylate (MMA), butyl acrylate (BA), acrylic acid (AA) and the branched polymer aqueous dispersions as comonomer. The particle size distribution of the branched polyacrylate emulsion was in the range of 100-200nm, surface tension stabilized at 30~35 mN/m, and it had film-forming prop- erty and the emulsion had good stability. This branched polyacrylate emulsion had low viscosi