新戊二醇在溶剂中溶解度的测定及关联-高校化学工程学报.PDF

第24 卷第3 期 高 校 化 学 工 程 学 报 No.3 Vol.24 2010 年 6 月 Journal of Chemical Engineering of Chinese Universities June 2010 文章编号：1003-9015(2010)03-0365-05 新戊二醇在溶剂中溶解度的测定及关联 周彩荣, 石晓华, 冯 伟, 王海峰 (郑州大学 化工与能源学院, 河南 郑州 450001) 摘 要：用带激光监视系统的可控升温速率的溶解度测定装置，测定了温度范围为286.85 ~ 332.75 K 常压下新戊二醇 在有机溶剂甲苯、乙酸丁酯、乙酸乙酯，丙酮、苯、甲苯：异丁醇(3:1 体积比) 、甲苯：异丁醇(13:2 体积比) 、异丁醇 中的固液相平衡数据。运用λh 方程和Apelblat 方程对所测物系的溶解度进行了关联，其结果表明溶解度方程在上述的 研究温度范围和浓度范围内适用，且λh 方程优于Apelblat 方程。新戊二醇在溶剂中的溶解度的测定与关联为新戊二醇 的工业生产、回收提纯以及理论研究提供了重要的固液相平衡数据。 关键词：新戊二醇；溶解度；固液相平衡；激光检测技术 中图分类号：O645.12 ；O623.413 文献标识码：A Measurement and Correlation of Solubilities of Neopentyl Glycol in Solvents ZHOU Cai-rong, SHI Xiao-hua, FENG Wei, WANG Hai-feng (College of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450002, China) Abstract: The solubilities of neopentyl glycol in different solvents, such as in toluene, butyl acetate, ethyl acetate, acetone, benzene, toluene:iso-butanol alcohol (3:1 V/V), toluene:iso-butanol alcohol (13:2 V/V) and iso-butanol alcohol, were measured by using laser monitoring technique at temperature range of 286.85 K to 332.7 K and under atmospheric pressure. The λh equation and Apelblat equation were adopted to correlate the experimental data, and the constant values of these two equations for neopentyl glycol solving in above solvents were determined. Using these two equations, the solubilities calculated are in good agreement with the experimental data, and the correlation results of λh equation is better than those of Apelblat equation. The solubility data and their correlation