纤维素是自然界存在最丰富的多醣类且可应用於食品和生物材料.DOC

國立宜蘭大學食品科學系碩士班專題討論 題目：球磨對降解纖維素微細結構之影響 Effect of ball milling on microstructure of degraded cellulose 研究生專題討論書面摘要 指導教授：陳輝煌 老師 報 告 者：陳束筠 報告日期：2007/ 球磨對降解纖維素微細結構之影響 摘要 降解纖維素使其粒徑下降並提高表面積，可促進化學反應的進行，降解過程中產生的水溶性纖維素或寡糖聚合物，對人類的健康也有很大的助益，因此本報告將介紹研磨條件對纖維素降解程度及微細結構的影響。纖維素具有高度結晶，以行星式球磨機球磨後，纖維素結晶的X-ray繞射強度隨著球磨時間增加而減少，使纖維素的不定形區增加。未經處理纖維素，分子內和分子間互相以OH基藉由氫鍵結合在一起，因此只有一小部份的OH基在纖維素表面可以和其它物質反應，纖維素球磨後，FTIR光譜中代表OH基拉伸振動(波長3200~3500 cm-1)的波峰變寬，顯示纖維素結晶度減少或聚合度降低，此乃氫鍵被破壞，造成纖維素微細化後表面積增加而有大量自由OH基暴露，有助於提高微細化纖維素的界面化學反應，易於形成新的復合材料。以微結晶纖維素(MCC)為例，使用Retsch 球磨機合適的濕式球磨條件為原料2 g、球珠尺寸12 mm、頻率18 HZ，球磨溫度對降低MCC粒似無顯著影響，MCC從球珠得到壓力後提供破碎能量，導致較大的球珠尺寸對降低MCC的粒徑 關鍵字：球磨、維晶纖維、傅利葉紅外光譜分析儀、結晶 Abstract Degradation of cellulose not only reduced the particle size but also increased its surface area and thus enhanced chemical reactions. Both of the water soluble cellulose and oligomers obtained in milling process exhibit a great deal of benefit to human health. The effect of milling on degradation and structure influence of cellulose will be introduced in this report. Cellulose is a very high crystalline polymer. After mechanical ball milling was performed in a planetary ball mill, the X-ray diffraction intensities of cellulose crystal decrease as milling time increase. The milling caused a marked decrease in the crystallinity, making the cellulose highly amorphous. In native cellulose, almost of the OH groups were bound to one another through intra- and inter-molecular H-bonds. Only a small number of the OH groups on the surface could react with other substances. The OH-stretching vibration region (3200 to 3500 cm-1) became broader in the FTIR spectra and is mainly associated with a decrease in the degree of crystallinity and/or polymerisation of the milled cellulose. The collapse of the inherent hydrogen bonds yields a great number of free OH groups on the resultant cellulose microparticles, which may have enhanced interfacial chemical reactions and then forms the new composite. The desirable operating conditions on the