基于光谱互补的无定形梯形聚合物的三元共混本体异质结聚合物太阳能电池-材料工程专业论文.docxVIP

AB ABSTRACT PAGE PAGE IV ABSTRACT Polymer solar cells as the third photovoltaic technique with the advantages of low cost and easy fabrication, its power conversion efficiency have exceeded 10%. But the conventional single donor binary blend polymer solar cells have been limited by the narrow range of light absorption and the photon harvest ability, so the power conversion efficiency is still low. Ternary blend solar cells are the extension and development of the traditional binary system，inherited the easy fabrication of the binary blend polymer solar cells, and utilized the different band gap of the two polymers as well, to enhance the light absorption. Finally, the power conversion efficiency could be improved by breaking the limitation of light absorption. However, both the chemical structure and the crystallinity properties are the parameters involving with the morphology, therefore, ternary blend poses complicated impact on the bulk heterojunction nanomorphology as compared to devices based on binary blends, imposing stringent requirements on the selection of appropriate materials and thereby limiting the development and application of ternary blend solar cells. Recently, numerous ladder-type polymers (LP) with various band gaps have been successfully applied in polymer solar cells. Owing to the out-of-plane side chains of LP inhibiting the ordered packing of polymer main chains, most of them exhibit amorphous nature. Thus, application of amorphous LP in bulk-heterojunction (BHJ) polymer solar cells can avoid the issue of morphology control and can easily regulate the light absorption range, regardless of controlling the BHJ micromorphology. Herein, we take advantage of the two kinds of ladder polymers (LP), poly(indacenodithienothiophene?dithienothiophenyldifluorobenzothiadiazole) (PIDTT-DFBT-TT, LP1), poly(indacenodithienothiophene?phenanthroquinoxaline) (PIDTT-PhanQ, LP2), and blend them with PC71BM, to fabricate the ternary blend devi