钾长石提钾机理研究及新工艺探讨-化学工艺专业论文.docxVIP

钾长石提钾机理研究及新工艺探讨摘 钾长石提钾机理研究及新工艺探讨 摘 要 本文综述了国内外铡长石提钾的研究现状，通过xRD、TG—DTA 等表征手段，对宁国地区钾长石进行了理化性能表征：并以Nacl、 CaCl2、SrCl2、BaCl2为添加剂，研究焙烧温度、添加剂用量对提钾 效果的影响，发现在添加剂熔点温度附近，提钾效果发生突变。用 xRD测试技术对钾长石焙烧前后及与添加剂共焙烧后的水不溶物进 行了物相分析。结果表明，铝硅氧网络结构未破坏，共焙烧提钾机 理为离子交换。与钾长石中钾离子交换能力大小顺序为： Na+ca2+s r2+Ba2+，与理论推测完全一致。其中，Nacl、caCl 2为 添加剂效果较好，高于熔点温度焙烧时，钾离子交换度皆在90％以 上。以离子交换机理为依据，开发出了反应条件比较温和的由钾长 石提钾新工艺，研究了助剂用量、反应温度、物料配比等因素对钾离子交 换度的影响，通过正交实验得出最佳工艺条件：温度250℃；助剂用量2．23ml： 配料比m(添加剂)：J11(钾长石)=1：l，钾长石中K20溶出率可达92％以上。用xRD 对水不溶物进行了物相分析，验证了新工艺反应机理属于离子交换。 关键词：钾长石提钾 离子交换反应机理 Studv Studv on IVIechanism and New Process of Potassium Extraction from Potash Feldspar Abstract This paper has summarized the research conditions of potash f色1dspar at China and abroad．The physical and chemicaI properties of potash feldspar of Anhui Ningguo have been characterized by XRD，TG—DTA etc．The extraction of potassium from potash feldspar with four additiVes NaCl，CaCl2，SrCl2 and BaCl2 has been studied．The calcinations temperature and the dose of additives that efkct the extraction of potassium were discussed，and great chan2es have been taken place on the efnciency of potassium extraction at near the melting points of additives．The phase conlpositions of potash f色ldspar and it’s calcined， and water insoluble substances of co—calcining of potash f色ldspar with additives were analyzed by XRD．The expe“ment results shOwn that the aluminsiloxane network structures were not damaged after calcinin如and the mechanism of potassium extraction by co．calcining was ion—exchange．It was shown that the order of exchange capab订ities of potassium extraction of additives was Na+CapS一+Ba”．which were consistent with that of theoretical Dredication． Furthermore，as the calcining temperature is over the melting points of NaCl or CaCl，．it was also shown that both of additives were much better than others and the potassium ion—exchange degrees were more than 90％．With the ion．exchan2e theory，a very gender reaction condition of new process has been researched． The ef