基于季铵盐阳离子表面活性剂的温敏型胶束体系的构筑及其性能分析-分析化学专业论文.docxVIP

聊城大学硕士学位论文 聊城大学硕士学位论文 ii ii （三）单链季铵盐阳离子表面活性剂与阴离子表面活性剂混合水溶液的胶束化 行为随温度变化的研究 考 察 了 单 链 季 铵 盐 阳 离 子 表 面 活 性 剂 3- 烷氧基 -2- 羟 丙 基 三 甲 基 溴 化 铵 (C14HTAB)水溶液中加入带反电荷的阴离子表面活性剂辛酸钠(SO)后形成的混合溶 液的流变性能。实验表明：组分配比对体系粘弹性影响很大，当改变环境温度和阳 离子表面活性剂链长时体系的粘弹性也可以得到调节。 （四）双链季铵盐阳离子表面活性剂与非离子表面活性剂混合水溶液的胶束化 行为随温度变化的研究 探究了双链季铵盐阳离子表面活性剂 2-羟丙基-1,3-十四烷基二甲基氯化铵与非 离子表面活性剂聚氧乙烯月桂醚混合水溶液的流变性随浓度和温度的变化情况。在 特定的浓度比例时，体系的粘度随着温度的增加出现了最大值现象。 关键词：季铵盐阳离子表面活性剂；添加剂；温度响应；微观结构；转化机理 iii iii ABSTRACT Construction of new intelligent micelles is a hot field in self-assembly chemistry by the amphiphilic molecules with specific functions and properties. In this paper, we intend to build stable micelle structure by the single and double chain surfactant-water-additives, utilizing multiple weak intermolecular interactions to construct thermosensitive intelligent micelles. The formation process of wormlike micelles, micellar structure transformation and temperature-switchable processes of intelligent mecellar systems will be determined by utilizing rheological measurement, and kinetic parameters for the processes will be obtained. Structure-activity relation between the aggregate structures and the important factors, including molecular structures of surfactants, countra-ion and additives, are to be systemically investigated by combining the kinetic properties with the electron microscopic, conductivity and nuclear magnetism technologies. The micellar formation mechanism, the micro-structure of the intelligent micelles, the rule of micellar structure transformation induced by temperature, and the effects of additives on the structure formation will be explored. These research works can reveal the interaction mechanism between the molecules in the process of intelligent micelle formation, and the synergistic interactions of various non-covalent forces from the point of view at molecular level, establish the new supramolecular structures and widen the type of and the function of assembly and deepen the understanding about the basic i