梯度乳液聚合制备核壳结构丙烯酸酯乳液合成工艺-中国科技论文在线.PDF

2OO6年12月 湖南师范大学自然科学学报 V01．29 No．4 第29卷第4期 Journal of Natural Science of Hunan Normal University Dee．．2006 梯度乳液聚合制备核壳结构丙烯酸酯乳液 — — 合成工艺 张心亚，孙志娟，傅和青，黄 洪，蓝仁华，陈焕钦 (华南理工大学化工与能源学院化学工程研究所，广州 510641) 摘 要 采用梯度种子乳液聚合方法，引入半连续单体滴加工艺和亲水性功能单体，制备了零VOC乳胶涂料 专用的具有较高玻璃化温度(t )、较低最低成膜温度( )的核／壳结构的纯丙烯酸酯乳液．讨论了合成工艺、乳化 剂种类和用量、亲水性功能单体及各阶段单体用量等因素对乳液结构及t 的影响．实验结果表明采用梯度种子乳 液聚台工艺和引入亲水性功能单体——甲基丙烯酸羟丙酯(}删雌)可有效地降低丙烯酸乳液的f (t 3℃)，提 高乳液的冻融稳定性和钙离子稳定性． 关键词 梯度乳液聚合；核壳结构乳液；最低成膜温度；玻璃化温度 中圈分类号 TQ630．1 文献标识码 A 文章编号 1000-2537(2006)04．0062．06 Study of Core-shell Structure Acrylate Emulsion Prepared by Gradual Emulsion Polymerization：Synthesis Technology ZI-tANG Xin-ya，SUN Zhi-juan，FU He-qing，HUANG Ho ，L4N Ren-hua，CHEN Hl1．an-qin (Research Institute of Chemical Engineering，South China University of Technology，Guangzhou，510641，China) Abaraet Core—shell acrylate锄lllsf0n for zero VOC latex coatings with higher glass transition temperature(tg)and lower minimal film·forming temperature( 眦)is prep~a by Gradual seeded Emulsion Polymerization and introducing hy- drophilic functional monomers．The main influence factors such as emulsion polymerization technology，emulsifier，hydro． philic functional monomers and different ration of core／shell monomer to COre—shell structure and tMF of polymer particle are discussed．The experimental results show that typical COre—shell structure acrylate emulsion with higher tg and lower t砸can be prepared by using gradual seeded emulsion polymerization．Hydrophilic functional monomer HPMA is effective to reduce the tMF of emulsion and enhance the thaw-freezing stability and electronic stability． Key words gradual emulsion po