焦化废水的氨氮处理-市政工程专业论文.docxVIP

pSlB2s2 p SlB2s2 焦化废水的氨氮处理+ 摘要 焦化废水成分复杂，氨氮浓度高，生物难降解有机物含量 高，水质、水量变化较大，而传统的活性污泥法生物处理工艺 对COD和NH。一N的去除效果不够理想，难以使出水达到排放标 准，给环境和人体带来危害。研究表明：利用厌氧酸化作为预 处理，反硝化一碳化一硝化作为二级生物处理，是一种经济而有 效的焦化废水脱氮处理工艺。 本试验研究中，先培养、驯化出6种降解难降解物质的优 势菌种和脱氮菌种，进行固定化后，分别投入碳化、硝化和反 硝化反应器，在各自的反应器中研究了难降解物质及NH。一N的 降解途径、降解过程分析及影响生物脱氮过程的各种因素，然 后将优势菌应用于焦化废水处理的复合型脱氮工艺中，并通过 研究脱氮工艺流程及运行参数，最后确定出最佳工艺为 A。一A：-O-M工艺，并选定本试验条件下的最佳工艺条件和运行 参数为：系统总HRT=51h，相应地，A。段HRT=10．5h，＆段 }山西省自然科学基金资助项目 HRT=12．5h，0段HRT=20h，M段HRT=8h；厌氧段pH值维持在 HRT=12．5h，0段HRT=20h，M段HRT=8h；厌氧段pH值维持在 6．5～7．5；混合液回流比R=3．5～5．0；在缺氧段加入甲醇作 为反硝化碳源，按BOD。：TN=10．6为宜；好氧段T维持在25～ 32。C，好氧0段pH值通过滴加NaHCO。控制在7．7～8．2，剩余 碱度为100～200mg／L，出水DO为2．0mg／L左右，M段pH值控 制在7．5～8．6，D0控制在6．59～6．83mg／L；好氧段进水COD 负荷不高于0．05(kgCOD／kgMLSS·d)，NH。一N污泥负荷不高于 0．01(kgNH。一N／kgMLSS·d)。在上述工艺条件下，系统对COD 和NH。一N的去除率分别在87．7～93．9和86．5～92．4，A。的反 硝化率达75％以上；当进水COB800mg／L，NHs—N260mg／L时， 出水COD100mg／L，NH。一N25mg／L，两个指标分别达《污水 综合排放标准》(GB8978—1996)一级和二级排放标准。 关键词：焦化废水，氨氮去除，优势菌，降解途径，膜法序批 式反应器，厌氧一缺氧一好氧一好氧 {山西省自然科学基金资助项目 AMMON AMMON I A N l TROGEN TREATMENT OF COKE PLANT WASTEWATER ABSTRACT Components were complex in coke plant wastewater,in which contains high concentration of ammonia nitrogen and a number of toxic and refractory organic compounds，and great changes happened usually to water quality and water flow．Most of the original treatment processes were conventional activated sludge method，though which the COD and ammonia nitrogen removal were not favorable and the emuent concentration couldn’t attain the wastewater drainage level，which brought severe harm to our environment and human body．It had been demonstrated that using anaerobic acidification as pretreatment and denitrification--carbonization--nitrification as secondary biological treatment to removal ammonia nitrogen in coke plant }山西省自然科学基金资助项目 wastewater wastewater was a cost effective technology In this research，firstly,six efficiency predominant bacteria of degradating refractory organic compounds and nitrogen removal bacteria after they were cultured and do