离子色谱法测定茶叶中草甘膦的残留-食品安全质量检测学报.PDF

7 5 Vol. 7 No. 5 2016 5 Journal of Food Safety and Quality May , 2016 黄嘉乐, 李秀英, 林森煜, 郭新东* (, 511447) 摘 要: 目的 方法 , Dionex OnGuard ⅡRP Dionex OnGuard ⅡAg/H , IonPac AS11-HC (AG11-HC ), KOH (EG), , 结果 0.006~12.5 mg/L (0.9998), 0.19 mg/kg, 0.64 mg/kg, 80.7%~98.1%, (n=6)1.8%~3.4%, (n=5)5%结论 , , GB 2763-2014 关键词: Determination of glyphosate residues in tea by ion chromatography * HUANG Jia-Le, LI Xiu-Ying, LIN Sen-Yu, GUO Xin-Dong (Guangzhou Quality Supervision and Testing Institute, Guangzhou 511447, China) ABSTRACT: Objective To establish a rapid and simple analytical method for the determination of glyphosate residues in tea by ion chromatography. Method The anionic impurities in the extraction solution were precipitated - with acetonitrile. The large molecules and Cl in the supernatant were removed by the Dionex OnGuard Ⅱ RP column and the Dionex OnGuard Ⅱ Ag/H column, respectively. The filtrate was separated on an IonPac AS-11 column with KOH solution as eluent. A suppressor with external water mode and a conductivity detector were used for the detection. Results Under the experimental conditions, the calibration curve of glyphosate was linear in the range of 0.006~12.5 mg/L, wi