金属锰在含碳耐火材料中的作用机理研究-钢铁冶金专业论文.docxVIP

内蒙古科技大学硕士学位论文摘 内蒙古科技大学硕士学位论文 摘 要 本文研究了金属Mn对碳材料中碳网络化结构形成的影响及其对含碳耐火材料性能 的影响。 以天然鳞片状石墨和Mn粉为原料，以酚醛树脂为结合剂制成^恤一C试样。对干 燥后试样进行差热分析后于930--1600℃烧成，然后采用XRD和SEM等分析手段对烧 成后试样进行物相组成和显微结构分析。XRD分析表明，Mn—C试样在烧成过程中会 形成一系列锰碳化合物，这些化合物是不稳定的过渡相化合物，随温度的升高逐渐发生 分解析出单质锰和碳。SEM分析表明，当试样中Mn和C的质量比为1：4，烧结温度为 1400℃时，Mn对碳形成网络化结构影响显著。 以烧结板状刚玉、锆莫来石、天然鳞片状石墨为原料，以酚醛树脂为结合剂， Mn、A1、Si、B4C粉为添加剂，经1450℃烧成后制成铝碳和铝锆碳试样。对其抗渣 侵蚀性能和抗氧化性能进行了研究，结果表明：在铝锆碳试样中，当Mn与越、si复 合加入且Mn与c的质量比为1：4时，试样抗渣侵蚀性能和抗氧化性能较好；当Mn与 si复合加入且Mn与C的质量比为3：7时，试样抗氧化性能较好。在铝碳试样中，当 Mn与Al、Si、B4C复合加入且Mn与C的质量比为1：4时，试样抗渣渗透性能较 好。 关键词：含碳耐火材料，锰，抗氧化性，抗渣侵蚀性 内蒙古科技大学硕士学位论文Study 内蒙古科技大学硕士学位论文 Study 011 the Influences of Manganese On the Structure and Properties of Carbon Refratories Abstraet n坨effect ofMn on the formation ofthe CdrbOll network structure i11 carbon materials and on the properties ofcarbon refi-actories have been investigated． The Mn—C specimens were fabricated using nattlral i]aky graphite and manganese powder as star曲g materials,phenolic resin as cement．n”specimens wel℃sintered at 930C through 1600℃．The thermal dynamic behavior was analyzed by using a DTAJrG thermal analyzer． The phase and microstructure of the specimens Wele studied by using XRD and SEM respectively．XRD analysis shows that a series ofMn carbide have been formed during sintering． Some Mn carbide decompose when the temperature increases．nle SEM observadon shows that the obvious influences ofMn On the formation ofcarbon network slructure occurred at the mass ratio ofmanganese to carbon of 1．4，and at the sintering temperature of 1400℃． A1203-C and A1203-ZrOz-C specimens were prepared using sintered tabular corundum, zirconia-mullite and natlLral flaky graphite as law materials，Mn,AI，Si，B4C additives and phenolic resin as cement．11豫specimens w啪sintered at 1450℃．Slay resistance and oxidation resistance ofthe A1203-C and A1203-Zr02-C specimens were studied．nle experiment results indicate that slay resistance and oxidation resistance of A1203-Zr02-C specimen is excellent when Mn,A1．Si are ad