金属改性海泡石催化降解VOCs机理及过程研究-环境工程专业论文.docxVIP

河北科技大学硕士学位论文 河北科技大学硕士学位论文 万 万方数据 万方数据 万方数据 AbstractVOCs Abstract VOCs is an important precursor of PM2．5 and ozone generation,VOCs is one of the mill causes of fog,SO it has very important significance for VOCs governance．Catalytic oxidation method can effectively put the volatile organic compounds in bw temperature processing,high efficient catalyst become the key of life．Low quality sepiolite is kind of natml zeolite．with a certain specific surface area，and the price is bw．But the lack of bw grade sepiolite high value-added product development．To solve above problems，this paper intends to develop bw quality sepiolite as catalytic carrier,load Iramition metal, catalytic oxidation of volatile organic compounds．To optimize the catalyst preparation process，to study the optimal sepiolite catalyst toluene degradation process，the activation energy calculation of sepiolite catalyst for catalytic oxidation of toluene． This study pretreatment purification of bw quality sepiolite by adding acid and hot wate r’purification of sepiorite．The pretreatment sepiolite was characterized by XRD TEM and BET．Characterization resuks shows that pretreatment of sepiolite has high purity,good dispersion and high specific surface area．Then to load coppe r，manganese Inetal oxide．It has excellent catalytic oxidation activity．The catalysts were characterized bv XRD，BET,TEM，EDX and active test．Active component load to the surface and porous internal of the sepiolite，copper-manganese spinel as active ingredient．In the spinal／sepiolite catalVSt has been studied in the mixed doping rare earth element cerium can enhance the catalytic activity of catalyst．When doping ratio is 0．2，its catalytic e街ciencv is highest．The life of the catalyst and the effect of space velocity of sepiolite catalyst is investigated．For the optimal sepiorite forming，compared with other molding efficiency ofcatalyst,sepiolite has good cost performance．This study using MVK model which based on the use of oxidation．reductio