金属有机配合物材料纳米线的研究-物理电子学专业论文.docxVIP

摘要摘要 摘要 摘要 自从Iijima发现纳米碳管以来，各种新颖的一维纳米材料如纳米管、纳米 线、纳米棒、纳米带和纳米同轴电缆等相继被发现，引起了国际上广泛的关注。 它们在纳米电子学、光子学、磁器件等方面有广阔的应用空间。 电荷转移型金属有机配合物是一种具有独特的电学、光学性质的有机功能 材料。用其制成的薄膜具有光致变色特性，可用于光存储；在其晶体的一个特定 方向施加一定电场会呈现负阻特性，且高、低两种电阻状态的电阻率相差105～ 10 7倍，即具有明显的开关效应。但是至今未见有将其制成纳米线(棒)的报道。 为了更好地了解电荷转移型金属有机配合物一维纳米结构的特性，我们进 行了初步地探索。本论文介绍了电荷转移型金属有机配合物纳米线的制备方法， 研究了它的电学和光学特性，并讨论了它在超高密度存储、场发射、光存储等方 面的应用前景。 本论文的具体贡献包括： 1．发明了一种新型金属有机配合物纳米线，并提出相应的制备方法——真空饱 和蒸气反应法。 2．研究了单根电荷转移型金属有机配合物纳米线的电学性质，发现它具有开关 特性和负电阻特性。 3．研究了电荷转移型金属有机配合物纳米线阵列的场致发射性质。发现它的开 启场强是3吼删，在5聊删的场强下场发射电流达到275pA／cm2，电流一电 压曲线符合Fowler-Nordheim(F-N)关系。 4．研制了用于电荷转移型金属有机配合物材料光学性质测试的系统，此系统还 可以作为光盘静态测试系统，完成了硬件组装和控制程序的编制。 关键词：一维纳米材料，电荷转移型金属有机配合物，电学性能，光学性能， 场致发射 摘要 摘要 ¨ Abstract Much attention has been focused on one-dimensional(1D)nanostructures—tubes， wires，rods，belts——whose lateral dimensions fall anywhere in the range of 1 to 100 nin ever since carbon nanotube was discovered by Ijima in 1991．Their peculiar and fascinating properties superior to their bulk counterparts provide US unlimited research opportunities in the fields ofnanoelectronics，optical and magnetic devices． Organometallic charge—transfer complex is a kind of organic functional materials with special optical and electrical pl operties．The erasable photochromatic effect of this complex Call be used in optical memory．Bistable electric switching property contributes to high density storage，Although much research has been devoted to this complex in the form ofbulk or thin film，little research has been done on the research of 1D nanostructure ofthis complex． To obtain a proper evaluation on the properties of 1D organometallic charge—transfer complex nanostructare，the present thesis was initiated．In this thesis， we reported the preparation method of organometallic charge—transfer complex nanowires，measured their optical／electrical properties，and discussed their potential application in the field ofhigh—density storage，field—emission and optical storage． The creative WOrk of也is thesis 1s as