晶态纳米碳基复合体的形貌控制及在电极材料中的应用-无机化学专业论文.docxVIP

? ? ? ＼11Y11111111111 ＼11Y11111111111＼Y1LIl911111114IllllUolllll2lllIl5lllIIllBIIII94025B 黑龙江大学硕士学位论文 Abstract Molybdenum carbide，tungsten carbide is a unique class by owning Pt—like catalytic activity in acid and Alkaline medium，high stability and resistance to CO gas poisoning and other features，which are widely used in catalytic hydrogenation, dehydrogenation,isomerization，fuel cells areas，etc．Especially in the direct methanol fuel celI(DMFC)，molybdenum carbide，tungsten carbide catalyst for methanol electro-oxidation respective are much less than Pt,but their participation is conducive to CO and other intermediate products desorpting from I t,thus greatly improving the catalytic activity of precious metals and stability,and reduce the amount of precious metals，thereby reducing the production cost of the direct methanol fuel cells． Therefore，the synthesis of molybdenum carbide，tungsten carbide。or their composite has very important significance．The traditional carbon materials have excellent physical transmission capacity,but its steric hindrance，it is not conducive to applications since its resistance is SO large．The crystalline nanocarbon materials、航m tIi曲conductivity and structural stability,is a very good optional material． In this paper,chitosan and polyacrylamide are used 懿 carbon source．Phosphomolybdic acid hydrate and tungstophosphoric acid are adopted as molybdenum and tungsten source，and Ni metal salt serve for graphitizing catalyst．By coordinating polar groups 011 the carbon source and metal iota，crystalline nanocarbon based composite materials is SUCCESS to be realized synchronous synthesis． By XRD，Raman，TEM，TG，BAS 1 00，and other physical and chemical characterization of the crystalline phase，morphology，phase transition and its direct methanol fuel cell(DMFC)application of each product．The experimental results show that the chitosan and polyacrylamide witll a large number of groups have a certain confinement effect for the growth of nano-particle