干酪素水解产物的膜分离.PDF

Vol. 26 No. 4 350 Journal of East China U niversity of Science and Technology 2000-0 : 1006-30 0( 2000) 04-0350-04 * 许学书 , 　王　宏, 　黄　慧, 　廖湘海, 　张嗣良 ( 华东理工大学国家生化工程技术研究中心, 上海200237) : 干酪素酶解产物为介质对膜分离进行了研究。讨论了碱性和中性条件下膜分离过程中 膜两侧浓度、流通量(J ) 和总氮截留率( R) 的变化。发现pH 值低污染度高, 截留分子量大的膜污染 度大。用0. 1mol/ L 的氢氧化钠和5mL/ L 的 4 消毒液浸泡洗涤可使膜的水通量恢复94% 。在干 酪素水解液的超滤中, 阻力主要来自于凝胶层。凝胶层的阻力比膜阻力大1 至2 个数量级。 : 膜分离; 酶解; 超滤; 干酪素 : T Q02 . : A Application of Membrane Reactor to Casein Zymohydrolysis - * , , , - , - X U X ue shu WA N G H ong H UAN G H ui LIA O X iang hai ZH A N G Si liang (N ational Engineering Research Center f or iotechnology ECUS T, Shanghai 200237, China) : . Abstract The membrane separation for casein zymohydrolysis w as studied The changes of concentra- tions on both sides of membrane under alkali and neutral conditions during the procedure w ere observed and discussed. The relationships betw een flux J and time t and betw een trapped ratios R of total nitrogen 1 1 2 and t for neutral and alkali conditions are: J = - 3. 192 3 ln t + 9. 627 9; R = 0. 11+ 0. 0 1 t; J = - 0. 375 4 + 4. 509 3; 2 = 0. 21- . 10- 6 , . ln t R t respectively The membrane contamination degree is . 94% larger at low er pH or higher MWCO membrane T he membrane flux can be recovered to reach by soaking membrane in the solution of 0. 1 mol/ L NaOH and 5mL/ L 4 disinfectant. T he resistance of the gel layer is of 1 to 2 order higher than that of the membran