脱氢枞酸单离方法的比较研究-生物质化学工程.PDFVIP

第42卷第3期 生摇 物摇 质摇 化摇 学摇 工摇 程 Vol.42 No.3 2008年5月 Biomass Chemical Engineering May2008 脱氢枞酸单离方法的比较研究 * 陈祖芬,祝远姣,陈小鹏 ,钟 华,刘雁 (广西大学化学化工学院, 广西 南宁 530004) 摘摇 要:以歧化松香为原料、气相色谱为分析手段进行了脱氢枞酸单离方法的比较。 分别采用胺化法、皂化法和超声波 强化胺化反应结晶耦合法单离脱氢枞酸,并对不同的歧化松香原料进行了单离脱氢枞酸的研究,实验结果表明,采用自 制的歧化松香为原料,超声波强化胺化反应结晶耦合法在40 益 时单离脱氢枞酸的效果最好,纯度达99.99%,收率达 55.37%,并用GC、UV、IR、熔点仪和旋光仪对所制备的高纯度脱氢枞酸进行了分析鉴定,实验值与文献值基本一致。 关键词:脱氢枞酸;单离;歧化松香 中图分类号:TQ351.471;O657摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 文章编号:1673-5854(2008)03-0009-04 Comparative Study on Isolation Methods of Dehydroabietic Acid CHEN Zu鄄fen,ZHU Yuan鄄jiao,CHEN Xiao鄄peng,ZHONG Hua,LIU Yan (School of Chemistry and Chemical Engineering,Guangxi University,Nanning530004,China) Abstract:The comparison of isolation methods of dehydroabietic acid was carried out,using disproportionated rosin as raw material by GC method. Dehydroabietic acid was isolated from disproportionated rosin by methods of amination,saponification and aminating reaction鄄crystallization enhancedwith ultrasonic wave,respectively. The isolating dehydroabietic acid from diffe鄄 rent kindsof disproportionatedrosinshasbeen investigated. Theresults showedthat themethodof aminatingreaction鄄crystalliza鄄 tion enhancedwith ultrasonicwavewasthebesttoisolatethedehydroabieticacidfromtheself鄄madedisproportionatedrosinatthe temperature of40 益. The purity of dehydroabietic acid preparedwas99.99%. Theyield of dehydroabietic acidwas55.37%. The high purity dehydroabietic acid prepared has been analyzed and confirmed by using GC,UV,IR,melting point instrument and polarimeter aswell. The results are in agreement with the values in literature. Key words:dehydroabietic acid;isolation;disproportionated rosin