基于天然棉纳米纤维复合材料的制备及光催化性能研究-化学工程专业论文.docxVIP

浙江理工大学硕士 浙江理工大学硕士专业学位论文 基于天然棉纳米纤维复合材料的制备及光催化性能研究 万方数据 万方数据 在可见光照射下，40min 几乎降解 99%的罗丹明 B。超细棉纳米纤维能抑制 CdS 的团聚，缓解 CdS 的光腐蚀现象。 3、棉纤维/CdS/TiO2 复合纳米材料的制备及光催化性能研究 利用水热的方法在棉纤维上合成花状 CdS 纳米晶，也就是花状结构的棉纤 维/CdS 复合纳米材料，研究了水热反应时间、温度、Cd : S 比对该复合材料的影 响。结果表明：当 Cd : S = 1 : 3 时在 200℃水热反应 12h 得到完美的花状结构复 合材料，并提出了其可能的形成机理。 以花状棉纤维/CdS 复合纳米材料为载体，控制钛酸四丁酯的量用溶胶-凝胶 的方法负载 TiO2 薄膜，制备一系列棉纤维/CdS/TiO2 复合纳米材料，作为对比， 制备了纯的花状 CdS，CdS/TiO2 纳米材料。对比结果表明：加入 10ml 钛酸四丁 酯的复合纳米材料具有最好的光催化降解罗丹明 B 的效率，并且有最好的稳定 性。捕获性实验证明：羟基自由基是该复合材料的主要活性物种。由此，提出了 其光催化降解罗丹明 B 的光催化机理。 关键词：天然棉纤维、静电纺丝技术、复合纳米材料、光催化 II Fabrication and Properties of Photocatalytic Nanomaterials based on Natural Cotton Cellulose Nanofibers Abstract Semiconductor photocatalyst cause extensive research due to its great potential applications in energy and environment. The traditional powder photocatalyst have some disadvantages of easy to aggregate in the preparation process of photocatalyst or dissolved in the dye waste, and not easily removed in the recycling process, easy to damage and other shortcomings limit its applications. Ultrafine nanofiber has advantages of a small size effect, large length to diameter ratio, a large specific surface area, light, soft and many other features. Furthermore, it has many hydroxyl groups on its surfaces, easy to modification, so it becomes competing carrier of inorganic nanomaterials. It not only enhancing stability of the nanomaterial, preventing their reunion, but also controling the size distribution of the nanomaterial. All these advantages make the inorganic material get better use in terms of optical, electrical and catalytic performance, evenly, there may produce a new exotic features. These kinds of composites Mutually complementarity fully make up for the shortcomings of a single material, produce new performances, and create a new situation in materials design. In this thesis, we revolves around work “Fabrication and Properties of Photocatalytic Nanomaterials based on Natural Cotton Cellulose Nanofibers”. T