基于嵌段聚合物模板的有序纳米粒子阵列的可控制备-材料学专业论文.docxVIP

ABSTRACT Ordered metal and metal oxide nanostructured arrays have attracted increasing interest due to their potential applications in photocatalytic, photoelectronic, sensors, solar cells, nanogenerator and data storage devices. Hereinto, how to fabricate these ordered arrays with controlled shape, size and position is a challenging problem. So far, block copolymer-bsaed lithography has received considerable attention because of the advantages to provide ordered arrays of 5～50 nm length scales with a simple low cost and scalable process. In this thesis, we study the controlled fabrication of well-defined nanostructured arrays under different conditions via block copolymer of polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP). Firstly, we investigate the self-assembly of block copolymer on silicon substrate in toluene and THF to obtain different periodicities of arrays of nanoparticles. Three different ways to introduce metallic ions have been explored. By changing the concentration and the type of metal precursor, we can obtain different sizes and types of arrays of nanoparticles. Furthermore, the effect of the substrate, such as silicon substrate, PDMS stamps replicated from CD and DVD templates on the resultant arrays has also been studied. Finally we develop a simple technique capitalizing on the multilayered arrangement of cylindrical domains to effectively double the pattern density templated by the block polymer. By controlling the solvent annealing condition, the concentration and the type of metal precursor, we can get different shapes, different sizes, different types of high density of ordered arrays of nanoparticles. KEY WORDS: Block Copolymer, Solvent Annealing, Self Assembly, Template, Ordered Arrays. PAGE PAGE 1 目 录 第一章 绪论 1 1.1 嵌段聚合物微相分离概述 1 1.2 嵌段聚合物在薄膜中的自组装 2 1.2.1 薄膜厚度对微相分离形貌的影响 3 1.2.3 链段间的相互作用力χ对微相分离形貌的影响 4 1.2.4 热诱导时间对微相分离形貌的影响 5 1.2.5 溶剂退火对微相分离形貌的影响 6 1.2.6 其他退火方法 8 1.3 嵌段共聚物微相分离的应用 9 1.3.1 制备纳米粒子图案 9 1.3.2 以沉积纳米粒子阵列为催化剂生长其他材料 1