基于速率型低温甲醇洗流程模拟-化学工程专业论文.docxVIP

Subject : Rate-Based Model and Simulation of Rectisol Process Specialt : Chemical engineering Name : Wang Dan (Signature) Instructor: Li Jianwei (Signature) ABSTRACT Removal of acid gases in the crude synthesis gas is to ensure continuous operation and stable quality on downstream products. The rectisol process is selected in most coal chemical plants, as it had the characteristics of cheap solvent, high purification degree and large handling capacity. In this thesis, the whole process is simulated and analyzed by Aspen Plus flowsheeting simulator software, according to a chemical plant. PSRK property method is adopted in thermodynamic equilibrium calculations. First, in order to study the influence of methanol temperature on the absorption, this paper calculated the solubility of various gases in methanol solvent at different temperature and pressure, and also the methanol vapor pressure at different temperature was calculated. The results show that the suitable temperature is in the range of -60 ℃ to -30 ℃ . This calculation method provided a simple and effective method for calculating the solubility, and which can be useful in the practical operation. Second, rate-based column models is selected in the process simulation, which calculated the methanol absorber, CO2 desorber, H2S concentration column, methanol regeneration column and methanol-water separation column, respectively. Then a detailed comparison with the plant data is done and analyzed, including temperature, pressure and composition of the important flows. The results showed that the errors are not more than 5 %. Third, a sensitivity analysis is canducted for liquid-gas ratio, methanol temperature and the composition of the feed to determine the minimum amount of methanol under varying operating conditions to enable purge gas to reach the target. It was analyzed that the absorber with different temperature of methanol required the amount of methanol. Hunting for the suitable temperature and pressure