光学与光谱学内容资料.pptVIP

仪器原理图 拉曼散射光谱 Raman scattering spectroscopy 某一频率的单色光经介质散射后出现其他频率散射光，且散射光频率与入射光频率之差和散射介质的某两能级差相对应的现象。 拉曼散射（Raman scattering），光通过介质时由于入射光与分子运动相互作用而引起的频率发生变化的散射。又称拉曼效应。1923年A.G.S.斯梅卡尔从理论上预言了频率发生改变的散射。1928年，印度物理学家C.V.拉曼在气体和液体中观察到散射光频率发生改变的现象。拉曼散射遵守如下规律：散射光中在每条原始入射谱线(频率为v0)两侧对称地伴有频率为v0±vi(i＝1，2，3，…）的谱线，长波一侧的谱线称红伴线或斯托克斯线，短波一侧的谱线称紫伴线或反斯托克斯线；频率差vi 与入射光频率v0无关，由散射物质的性质决定，每种散射物质都有自己特定的频率差，其中有些与介质的红外吸收频率相一致 拉曼分类 自发拉曼（Spontaneous Raman scattering ） 共振拉曼（Resonance Raman scattering ） 表面增强拉曼（surface-enhanced Raman scattering） 受激拉曼(Stimulated Raman scattering) 相干反斯托科斯拉曼（coherent anti-Stokes Raman scattering ） 拉曼光活性光谱（Raman optical activity） 针尖拉曼（Tip-enhanced Raman spectroscopy） 应用广泛： 在化学、材料、物理、高分子、生物、医药、地质、考古等领域有广泛的应用。 Raman microspectroscopy system High pressure techniques and applications Index 1、In-situ high-pressure techniques 2、High pressure Raman investigations on Fermi resonance 3、High pressure investigations onπ-π and CH-π interaction 1、In-situ high-pressure techniques P-T-X Three dimensions in science Water has 20 phases in the pressure range between 0 to 300GPa, at 0.03-6000K. Diamond windows on materials 1.Super conductivity 2.Weak interactions 3.Hydrogen storage 4.Metalization 5.Super hard materials 6.Amorphous 7.Geological simulation Diamond anvil cell Diamond cell Apparatus for extreme condition generation In-situ high pressure equipments 2、High pressure Raman investigations on Fermi resonance biphenyl,benzene,CCl4,CS2, 4,4’biphydine Weak Fermi resonance: P-trephenyl ,2,2’bipyridine 2、High pressure Raman investigation on the Fermi resonance of biphenyl Raman spectra of biphenyl have been obtained to pressures of 15GPa. The results indicated that with the increase of pressure, the effect of inter- and intra-molecular π-πconjugation and delocation increases, intensity enhancement of the Raman bands, accompany by the blue shift of the frequency. Intensity ratio(R f/a) of Two Fermi resonance bandsυ6’+ υ1’ and υ8’ decrease, and the f