介孔氧化锆提高负载费托合成钴催化剂清洁柴油产率.pdf

2010年 6月 湖南师范大学自然科学学报 Vol. 33　No. 2 　　　　　　　　 　 　　　　　　　　 　 第 33卷 第 2 期 Jou rnal of N atu ral Science of Hunan Norm al Un iversity Jun. , 20 10 　　　　　　　　　 Im provem en t of Y ield of C lean D iesel O il from M esoporous Z ircon ia Supported Coba lt Ca ta ly st for F ischerTropsch Syn thesis 1 1 2 2 2 1 2 L IU Ya chun , FU Z a ihu i , J IA L itao , CHEN J ian g ang , L I D ebao , YIN D u lin , SUN Yu han ( 1. Key L ab of R e source s F ineProcessing and A dvanced M aterials of Hunan Province, Key L aboratory of Chem ical B io logy and Traditional Ch ine se M edicine R e search (M in istry of Education) , College of Chem istry and Chem ical Engineering, Hunan Norm al U n iversity, Changsha 4 10081, Ch ina; 2. State Key L aboratory of Coal Conversion, In stitute of Coal Chem istry, Ch inese A cadem y of Sciences, Taiyuan 03000 1, Ch ina) A b stract　H erein , an app roach for the developm en t of novel cobalt catalyst w ith the h igh activity and selec tivity to the clean die sel o il fraction ( C12 ～C18 ) is reported. In the p re sen t work , a comp arative study of m e so porou s zircon ia, m e soporou s silica ( SBA 15) and conven tional zircon ia supported cobalt catalysts for FTS ha s been carried ou t. It wa s found that the cobalt catalyst supported on such a m e soporou s zirco