过渡金属和有机胺修饰的新型多酸化合物-无机化学专业论文.docxVIP

IV IV 了磁性研究，表明其具有典型的顺磁性。 关键词：多金属氧酸盐；无机-有机杂化化合物；晶体结构；合成方法 PAGE PAGE VI Abstract Recently, the design and synthesis of inorganic-organic hybrid compounds, which introduced transition metals/alkaline-earth as charge-compensation, polyoxometalates (POMs) as template blocks, are of great interest owing to their intriguing structures and potential applications in catalysis, optics, biological medicine and materials. In this thesis, nine new POMs, based on polyoxoanions and appropriate transition metal cations or organic ligands, have been synthesized under the conventional aqueous and hydrothermal reaction methods. These complexes are determined by single crystal structure X-ray diffraction and characterized by elemental analysis, IR, XPS, thermal properties, fluorescence spectroscopy, cyclic voltammograms and magnetic properties. The main works are as follows: Based on Keggin-type POMs as template, transition metal-Cu, Et3N, phen and flexile ligand bpp as bridging cations, 4 new supramolecular compounds were structured, respectively. 10[HN(C2H5)3]3[N(C2H5)3]2H2[PW VIW2 10 VO40]·2H2O (1) [Cu(phen)(H2O)3]0.5[Cu(phen)2(H2O)][PMo12O40] (2) [Hbpp]3[PW12O40] (3) [Cu(bpp)]2[Cu2(bpp)3][SiW12O40] (4) All of these supramolecular assemblies are built upon extensive hydrogen bonding interaction. Compound 1 contains a supramolecular inclusion structure through hydrogen bonds directing organic molecular Et3N and anions arranged orderly. Compound 4 with 2D wave-type layer is a bi-supported silico-tungstate modified by copper-bpp. Based on pseudo-Dawson type polyoxoanions, organic molecules bpe and bpp as bridging cations, two pseudo-Dawson type inorganic-organic compounds have been gained via hydrothermal method, respectively. (H2bpe)3.5H2[SbW18O60]·5H2O (5) [Cu2(Hbpp)4](H2bpp)0.5H2[SbW18O60]·3H2O (6) Based on tri-lacunary Keggin anions [AsW9O34]9- as template, introduced transition metals cobalt and nickel, three TMSPs sandwich-type compounds have been gained. Na10[Co4(A