过渡族金属化合物原位生长及其在锂离子电池中的应用-机械工程专业论文.docxVIP

万方数据 万方数据 Abstract Transition metal compounds show potential application as anode for Li-ion batteries owing to their high theoretical capacity (500~1000 mAh g-1) based on a novel redox reaction mechanism. However, they suffer from low electronic conductivity and structure destruction in cycling, which results in unsatisfied electrochemical performance. Improving the electronic conductivity and structure integrity in cycling are the key issues to enhance the electrochemical performance of transition metal compounds. Three dimensional porous metal foams show good electronic conductivity and structure stability, which can distinctly improve the electrochemical performance of transition metal compounds when using as composite electric substrates. In this paper, we report the preparation of transition metal compounds on Ni and Cu foams via in situ methods. The electrochemical performance of the composite materials as non-binder anodes for Li-ion batteries and the inner factors that affect the electrochemical performance was studied. The results are as follows: NiO/Ni and Li3VO4/Ni composite architecture were prepared via hydrothermal pretreatment and subsequent sintering using Ni foam as substrate. After 100 cycles at 0.15 C, the charge and discharge capacities of NiO/Ni are 704 and 721 mAh g-1, respectively. After 60 cycles at various rates from 0.06 to 10 C, the discharge capacity of NiO/Ni can restore to 745 mAh g-1 when lowering the current to 0.06 C. The excellent electrochemical performance of the NiO/Ni originates from electrochemical activation and electrochemical reconstruction that lead to the formation of a new porous architecture in cycling; After 100 cycles at 0.3 C, the charge and discharge capacities of Li3VO4/Ni are 378 and 379 mAh g-1, respectively. After 50 cycles at various rates from 0.4 to 15 C, the discharge capacity of Li3VO4/Ni can restore to 404 mAh g-1 when lowering the current to 0.4 C. The excellent electrochemical performance of the