过渡金属掺杂Pt基及Pd基催化剂的制备及其电催化性能研究-工业催化专业论文.docxVIP

万方数据 万方数据 of electrochemical surface area (ECSA) and the improvement of Pt particles efficience. Electrically Strong electron-donate effect of second metal decreases Pt2+ ions concentration and increases Pt0 surface concentration. The action of geometrical and electrical effects are responsible for high activities and stabilities of Pt-Co/C and Pt-Ni/C catalysts. Meanwhile, Pd-M/C (M=Fe, Co, Ni) catalysts shown good performance in formic acid electrocatalytic oxidation in following order: Pd/C Pd-Fe/C Pd-Ni/C Pd-Co/C. The addition of the second element to some extent decrease the size of Pd particles and improve the dispersion of active metal. In addition, Pd-based catalysts shown higher activities than Pt-based catalysts in formic acid electrocatalytic oxidation. Chitosan-modified Pt catalyst and Pd catalyst exhibited higher catalytic activity and better stability than unmodified catalysts for methanol and formic acid oxidation. The improvement of metal dispersion attributes to good ability capturing Pt or Pd particles of chitosan and inhibiting the aggregate of metal particles. Key words: Pt-based catalyst; Pd-based catalyst; transition metal; methanol; formic acid; electrocatalytic oxidation 3 目 录 摘 要1 Abstract 2 第一章 绪 论1 1.1 直接甲醇燃料电池简介1 HYPERLINK \l _TOC_250011 1.1.1 Pt 基电催化剂对甲醇氧化的研究现状 2 HYPERLINK \l _TOC_250010 1.1.2 DMFC 研究中的主要问题 3 1.2 直接甲酸燃料电池简介4 HYPERLINK \l _TOC_250009 1.2.1 Pt 基电催化剂对甲酸氧化的研究现状 4 HYPERLINK \l _TOC_250008 1.2.2 Pd 基电催化剂对甲酸氧化的研究现状 5 HYPERLINK \l _TOC_250007 1.2.3 DFAFC 研究中的主要问题 6 1.3 论文构思6 参考文献8 HYPERLINK \l _TOC_250006 第二章 炭黑负载 Pt-Ni 催化剂的制备及优化 13 2.1 实验部分 13 HYPERLINK \l _TOC_250005 2.1.1 炭黑负载 Pt-Ni 催化剂的制备 14 HYPERLINK \l _TOC_250004 2.1.2 Pt-Ni/C 催化剂的表征 14 2.1.3 电化学测试14 2.2 结果与讨论 15 HYPERLINK \l _TOC_250003 2.2.1 还原溶液 pH 值制备 Pt-Ni/C 催化剂对甲醇氧化的电催化性能影响 15 HYPERLINK \l _TOC_250002 2.2.2 不同负载量的 Pt-Ni/C 对甲醇氧化的电化学性能影响 17 HYPERLINK \l _TOC_250001 2.2.3 不同原子比的 Pt-Ni/C 对甲醇氧化的电化学性能影响 19 2.3 小 结 21 参考文献 22 HYPERLINK \l _TOC_250000