含氟润滑油超光滑表面防覆冰性能研究-材料工程专业论文.docxVIP

浙江工业大学硕士学位论文 浙江工业大学硕士学位论文 万方数据 万方数据 含氟润滑油超光滑表面防覆冰性能研究 摘 要 防覆冰意义重大。目前防冰技术中的热力和机械防冰除冰浪费能 源，化学防冰危害环境，相比之下，涂层防冰最近备受重视，其中超 疏水涂层更是热门研究方向。但最近人们发现，超疏水涂层表面机械 性能普遍较差，抗结冰效果有限。基于此，人们开始关注另一种防覆 冰涂层——润滑油灌注形成的超光滑表面（SLIPS）。 本文首先将稳定、超光滑的全氟聚醚润滑油滴加到高度疏水、具 有微粗糙结构的纳米 SiO2/氟硅溶胶/环氧树脂涂层中。发现由于润滑 油的引入，涂层降低了水滴滚动角，有效延缓了冰对表面的覆盖，防 覆冰性能大大提升，对冰的粘附力相比未填充润滑油的高度疏水表面 降低了一个数量级，抗结冰和疏冰效果均明显。 但上述润滑油/纳米 SiO2/环氧树脂涂层表面在经过多次的模拟 冻雨测试之后，防覆冰性能减弱。故我们又制备了含有贯通多孔结构 的短玻纤/氟硅溶胶/环氧涂层并灌注全氟聚醚润滑油。发现这种涂层 在抗结冰和疏冰性能上的表现比润滑油灌注的 SiO2 涂层更加出色。 同时，抗结冰性能的持久性也比 SiO2 涂层有了很大的提高。 关键词：防覆冰，全氟聚醚，超光滑，涂层 The study of anti-icing performance of ultra smooth surface infuse with fluorinated lubricant ABSTRACT Anti-icing is of great significance. Currently used active chemical, thermal, and mechanical techniques of ice removal are time-consuming and costly. Recent efforts for developing ice-phobic surfaces have been mostly devoted to utilizing anti-icing coating technology, especially super-hydrophobic coating, yet these surfaces fail in the extreme conditions, such as under the effect of shear stress. To address these problems mentioned above, the concept of slippery liquid-infused porous surface (SLIPS) was proposed. At first, we drop the stable, ultra smooth perfluorinated polyether lubricant into the nano-SiO2 / fluorine silicon sol/epoxy resin coating with high hydrophobicity and micro rough structure. Found due to the introduction of lubricant, the rolling angle of water gets smaller. What’s more, we demonstrate that SLIPS-coated surfaces not only suppress ice accretion by effectively removing sub-cooled water but also exhibit at least an order of magnitude lower ice adhesion than hydrophobic materials. But the anti-icing of the lubricating oil/nano-SiO2/ epoxy coating reduces after several simulation test of freezing rain. So we create a porous substrate containing short glass fiber/fluorine silicon sol/epoxy, then infuse with perfluorinated polyether lubricate. Found the performance of anti-icing better than the SiO2 coating infused with